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Valence isomerization of 2-phospha[1.1.0]bicyclobutanes

Autor: Slootweg, J.C., Krill, S., De Kanter, F.J.J., Schakel, M., Ehlers, A.W., Lutz, M., Spek, A.L., Lammertsma, K.

Publikováno v: Slootweg, J C, Krill, S, De Kanter, F J J, Schakel, M, Ehlers, A W, Lutz, M, Spek, A L & Lammertsma, K 2005, ' Valence Isomerization of 2-phospha[1.1.0]bicyclobutanes ', Angewandte Chemie International Edition in English, vol. 117, pp. 6737-6740 .
Angewandte Chemie International Edition in English, 44, 6579-6582. John Wiley and Sons Ltd
Slootweg, J C, Krill, S, De Kanter, F J J, Schakel, M, Ehlers, A W, Lutz, M, Spek, A L & Lammertsma, K 2005, ' Valence isomerization of 2-phospha[1.1.0]bicyclobutanes ', Angewandte Chemie International Edition in English, vol. 44, pp. 6579-6582 . https://doi.org/10.1002/anie.200502248
Angewandte Chemie International Edition in English, 117, 6737-6740. John Wiley and Sons Ltd

(Figure Presented) Remarkably stable 2-phosphabicyclo-[1.1.0]butanes (see picture; O red, P violet, W turquoise) were synthesized from the complexed phosphinidene Ph-P=W(CO)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::2d4ba2b079ab5b8f7e58cb4ed89e5fc8
https://hdl.handle.net/1871.1/0a72a404-0bbe-43b2-bb79-655a75f47ffa

Phosphinidene addition to conjugated allenes

Autor: Bertini, F., Wit, J.B.M., Ünal, M., de Kanter, F.J.J., Schakel, M., Slootweg, J.C., Ehlers, A.W., Nijbacker, T., Komen, C.M.D., Lutz, M., Spek, A.L., Lammertsma, K., Rontgen participation programme, Sub Crystal and Structural Chemistry, Crystal and Structural Chemistry

Publikováno v: Advanced synthesis & catalysis, 351(7-8), 1132. Wiley-VCH Verlag

Generating the transient electrophilic tungsten pentacarbonyl-phenylphosphinidene complex PhPW(CO)5 in the presence of 2,7-dimethylocta-2,3,5,6-tetraene leads to the formation of a 3,4-disubstituted phosphole or a complexed phospholene, depending on

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=narcis______::0965733f41a5321dce5dcb19d5599b11
https://dspace.library.uu.nl/handle/1874/44347

Fused tricyclic phosphiranes - analysis of phosphorus chemical shieldings

Autor: Couzijn, E.P.A., Ehlers, A.W., Slootweg, J.C., Schakel, M., Krill, S., Lutz, M., Spek, A.L., Lammertsma, K.

1,2-Addition of transient W(CO)5-complexed phosphinidenes exo to hexamethyl Dewar benzene affords the novel 3-phosphatricyclo[3.2.0.02,4]hept-6-ene complexes. The fused tricyclic phosphiranes are obtained as both the Z and the thermally less stable E

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od_______101::ccfa94a01faf5dddaa98f22ae08217b6
https://dspace.library.uu.nl/handle/1874/33088

Acetylene-Substituted Phosphane Oxides: Building Blocks for Macrocycles

Autor: Assema, S.G.A., de Jong, G.B., Ehlers, A.W., de Kanter, F.J.J., Schakel, M., Spek, A.L., Lutz, M., Lammertsma, K., R¿ntgenparticipatieprogramma, Dep Scheikunde

Publikováno v: European Journal of Organic Chemistry, 2405. Wiley-VCH Verlag
STARTPAGE=2405;ISSN=1434-193X;TITLE=European Journal of Organic Chemistry

Phosphorus-based macrocycles with acetylenic scaffolds have been built from acetylene-substituted phosphane oxides that were formed from diisopropylphosphoramidic dibromide (3) and an acetylenic Grignard reagent. The fourand six-edged macrocycles 15

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=narcis______::3a7c054b8722e55652f6a5c25a8f02a4
https://dspace.library.uu.nl/handle/1874/26891