Evidence of Sulfur Non‐Innocence in [CoII(dithiacyclam)]2+‐Mediated Catalytic Oxygen Reduction Reactions

Autor: Battistella, Beatrice, Iffland‐Mühlhaus, Linda, Schütze, Maximillian, Cula, Beatrice, Kuhlmann, Uwe, Dau, Holger, Hildebrandt, Peter, Lohmiller, Thomas, Mebs, Stefan, Apfel, Ulf‐Peter, Ray, Kallol

In many metalloenzymes sulfur-containing ligands participate in catalytic processes, mainly via the involvement in electron transfer reactions. In a biomimetic approach, we now demonstrate the implication of S-ligation in cobalt mediated Oxygen Reduc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c7679546cbaa9120db02eb02e228f5a7
https://publica.fraunhofer.de/handle/publica/429819

Evidence of Sulfur Non‐Innocence in [Co^II(dithiacyclam)]²⁺‐Mediated Catalytic Oxygen Reduction Reactions.

Autor: Battistella, Beatrice, Iffland‐Mühlhaus, Linda, Schütze, Maximillian, Cula, Beatrice, Kuhlmann, Uwe, Dau, Holger, Hildebrandt, Peter, Lohmiller, Thomas, Mebs, Stefan, Apfel, Ulf‐Peter, Ray, Kallol

Publikováno v: Angewandte Chemie International Edition; Feb2023, Vol. 62 Issue 6, p1-7, 7p

Evidence of Sulfur Non-Innocence in [Co ^II (dithiacyclam)] ²⁺ -Mediated Catalytic Oxygen Reduction Reactions.

Autor: Battistella B; Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany., Iffland-Mühlhaus L; Faculty of Chemistry and Biochemistry, Ruhr-Universität Bochum, Universitätsstraße 150, 44780, Bochum, Germany., Schütze M; Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany., Cula B; Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany., Kuhlmann U; Institut für Chemie, Fakultät II, Technische Universität Berlin, Straße des 17. Juni 135, 10623, Berlin, Germany., Dau H; Institut für Physik, Freie Universität zu Berlin, Arnimallee 14, 14195, Berlin, Germany., Hildebrandt P; Institut für Chemie, Fakultät II, Technische Universität Berlin, Straße des 17. Juni 135, 10623, Berlin, Germany., Lohmiller T; Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany.; EPR4Energy Joint Lab, Department Spins in Energy Conversion and Quantum Information Science, Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Albert-Einstein-Str. 16, 12489, Berlin, Germany., Mebs S; Institut für Physik, Freie Universität zu Berlin, Arnimallee 14, 14195, Berlin, Germany., Apfel UP; Faculty of Chemistry and Biochemistry, Ruhr-Universität Bochum, Universitätsstraße 150, 44780, Bochum, Germany.; Department for Electrosynthesis, Fraunhofer Institute for Environmental, Safety and Energy Technology UMSICHT, Osterfelder Str. 3, 46047, Oberhausen, Germany., Ray K; Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489, Berlin, Germany.

Publikováno v: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2023 Feb 01; Vol. 62 (6), pp. e202214074. Date of Electronic Publication: 2022 Dec 29.