(η2,η2-Cycloocta-1,5-diene)[2-(diphenylphosphanylmethyl)pyridine-κ2N,P]rhodium(I) tetrafluoridoborate 1,2-dichloroethane monosolvate

Autor: Siping Wei, Saskia Möller, Detlef Heller, Hans-Joachim Drexler

Publikováno v: IUCrData, Vol 1, Iss 8, p x161318 (2016)

The title compound, [Rh(C8H12)(C18H16NP)]BF4 has been prepared as a precatalyst for applications in rhodium-catalysed additions of carbocyclic acids to terminal alkynes leading to anti-Markovnikov Z-enol esters. Here the triclinic pseudopolymorph of

Externí odkaz: https://doaj.org/article/2fee0f3f15254784a573b5f9049d2897

Activation, Deactivation and Reversibility Phenomena in Homogeneous Catalysis: A Showcase Based on the Chemistry of Rhodium/Phosphine Catalysts

Autor: Moritz Horstmann, Detlef Heller, Hans-Joachim Drexler, Saskia Möller, Elisabetta Alberico

Publikováno v: Catalysts (2019). doi:10.3390/catal9070582
info:cnr-pdr/source/autori:Alberico Elisabetta, Möller Saskia, Horstmann Moritz, Drexler Hans-Joachim, Heller Detlef/titolo:Activation, Deactivation and Reversibility Phenomena in Homogeneous Catalysis: A Showcase Based on the Chemistry of Rhodium%2FPhosphine Catalysts/doi:10.3390%2Fcatal9070582/rivista:Catalysts/anno:2019/pagina_da:/pagina_a:/intervallo_pagine:/volume
Catalysts, Vol 9, Iss 7, p 582 (2019)

In the present work, the rich chemistry of rhodium/phosphine complexes, which are applied as homogeneous catalysts to promote a wide range of chemical transformations, has been used to showcase how the in situ generation of precatalysts, the conversi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e6c9705b06acf396c52c3ec3f4f6ee08

Monomerisation of [Rh2(1,3-bis-(diphenylphosphino)-propane)2(µ2-Cl)2] detected by pulsed gradient spin echo spectroscopy and 31P NMR monitoring of metathesis experiments

Autor: Saskia Möller, Detlef Heller, Alberto Mannu, Monica Ferro

A pulsed gradient spin echo experiment on [Rh2(1,3-bis-(diphenylphosphino)-propane)2(μ2-Cl)2] complex has been conducted in order to shed light on the supposed monomerisation process of [Rh2(diphosphine)2(μ2-Cl)2] complexes in solution. Such a proc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d54664aaf75755f9ef51fd244f9c04bb
http://hdl.handle.net/2318/1735704

Catalyst Deactivation During Rhodium Complex‐Catalyzed Propargylic C−H Activation.

Autor: Möller, Saskia¹ (AUTHOR), Jannsen, Nora¹ (AUTHOR), Rüger, Julia¹ (AUTHOR), Drexler, Hans‐Joachim¹ (AUTHOR), Horstmann, Moritz¹ (AUTHOR), Bauer, Felix² (AUTHOR), Breit, Bernhard² (AUTHOR) bernhard.breit@chemie.uni-freiburg.de, Heller, Detlef¹ (AUTHOR) detlef.heller@catalysis.de

Publikováno v: Chemistry - A European Journal. 10/7/2021, Vol. 27 Issue 56, p14034-14041. 8p.

Herausforderung für den ASEAN Way: Myanmars ASEAN-Mitgliedschaft

Autor: Oliver Wagener

Die Association of Southeast Asian Nations (ASEAN) hat sich in ihrer 37jährigen Geschichte den Ruf der erfolgreichsten Organisation staatlicher Kooperation der Asien-Pazifik-Region erworben. Als Garant des Erfolges wird immer wieder die diplomatisch