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Publikováno v:
Organic Letters. 22:666-669
A catalytic conjunctive cross-coupling reaction is developed that allows the construction of chiral organoboronic esters from alkylboron ate complexes and alkyl iodide electrophiles. The process occurs most efficiently with a Ni/Pybox-comprised catal
Publikováno v:
Org Lett
A catalytic conjunctive cross-coupling reaction is developed that allows the construction of chiral organoboronic esters from alkylboron ate complexes and alkyl iodide electrophiles. The process occurs most efficiently with a Ni/Pybox-comprised catal
Autor:
Sophie Hameury, Felix Riehle, Michael Sommer, Hannah Buchheit, Michael Walter, Fabian Kempe, Sarah Noemi Momm, Oliver Brügner
Publikováno v:
Angewandte Chemie. 130:1009-1012
A simple and high‐yielding route to tough polyarylenes of the type poly(meta,meta,para‐phenylene) (PmmpP) is developed. PmmpP is tough even in its as‐synthesized state which has an intermediate molar mass of Mw≈60 kg mol−1 and exhibits outs