Zobrazeno 1 - 10
of 49
pro vyhledávání: '"Sankaranarayana Pillai Sarish"'
Autor:
Carola Schulzke, Debasis Koley, Herbert W. Roesky, Ramachandran Azhakar, Prinson P. Samuel, Sankaranarayana Pillai Sarish, Anukul Jana
Publikováno v:
European Journal of Inorganic Chemistry. 2011:5006-5013
The reaction of PhC(NtBu)2SiCl (L) with N2O afforded the trimer {PhC(NtBu)2Si(O)Cl}3 (1), which contains a Si3O3 six-membered ring. In the molecular structure of 1, the PhC(NtBu)2 moieties are arranged around the Si3O3 six-membered ring in a paddle-w
Autor:
Jakob Hey, Sankaranarayana Pillai Sarish, Ramachandran Azhakar, Herbert W. Roesky, Dietmar Stalke
Publikováno v:
Organometallics. 30:2897-2900
The reaction of two highly reactive species, the silylene [CH{C(Me)NAr}- {C(dCH2)NAr}Si] (L, Ar = 2,6-iPr2C6H3) and the phosphorus ylide MeC(O)CHPPh3, resulted in the formation of 1, involving regiospecific Calkyl H bond activation. Compound 1 was ch
Autor:
Herbert W. Roesky, Sankaranarayana Pillai Sarish, Debasis Koley, Ramachandran Azhakar, Jakob Hey, Dietmar Stalke, Gašper Tavčar
Publikováno v:
Inorganic Chemistry. 50:3028-3036
Three silicon centered spirocyclic compounds 1-3, possessing silicon fused six- and five-membered rings have been prepared by the reaction of NHSi (L) [L = CH{(C=CH(2))(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}Si] with benzoylpyridine, diisopropyl azodicarboxyla
Publikováno v:
Accounts of Chemical Research. 44:157-170
Victor Grignard's Nobel Prize-winning preparation of organomagnesium halides (Grignard reagents) marked the formal beginning of organometallic chemistry with alkaline earth metals. Further development of this invaluable synthetic route, RX+Mg→RMgX,
Autor:
Birger Dittrich, Anukul Jana, Carola Schulzke, Carlos Enrique Abad Andrade, Sankaranarayana Pillai Sarish, Herbert W. Roesky, Prinson P. Samuel
Publikováno v:
Organometallics. 30:912-916
The dehydrohalogenation of a silicon(IV)-substituted diphenyl hydrazone derivative leads to a dimer of a N-substituted hydrosila hydrazone, which consists of a four-membered Si2N2 core and a hydrogen attached to each of the silicon atoms instead of g
Autor:
Anukul Jana, Thomas Schulz, Sankaranarayana Pillai Sarish, Dietmar Stalke, Herbert W. Roesky, Bijan Nekoueishahraki
Publikováno v:
Chemistry - A European Journal. 17:890-894
[L(1) AlMe]⋅THF (1; L(1) =CH[C(CH(2) )](CMe)(2,6-iPr(2) C(6) H(3) N)(2) ) is prepared by a new method to test its reactivity towards metal complexes to give heterobimetallic or polymetallic complexes. The treatment of 1 with germanium chloride ([LG
Autor:
Sankaranarayana Pillai Sarish, Fabio Dall'Antonia, Thomas Schulz, Herbert W. Roesky, Andreas Stasch, Kathrin Meindl, Dietmar Stalke
Publikováno v:
Chemistry - An Asian Journal. 4:1451-1457
The synthesis of N-heterocyclic carbene adducts of alkynyl lithium and magnesium is achieved, and different degrees of association are observed. Reaction of strontium amide nacnacSrN(SiMe(3))(2)(thf) (nacnac = CH(CMe2,6-iPr(2)C(6)H(3)N)(2)) with PhC[
Autor:
Dietmar Stalke, Daniel Stern, Carola Schulzke, Bijan Nekoueishahraki, Sankaranarayana Pillai Sarish, Herbert W. Roesky
Publikováno v:
Angewandte Chemie International Edition. 48:4517-4520
Bi-O chemistry: A direct regioselective route to bismuth bis(amino)naphthalene compounds, incorporating Bi-O and Bi-C bonds is described, in which an amide precursor is treated with aldehydes, ketones, alkenes, and alkynes, leading to insertion into
Autor:
Herbert W. Roesky, Michael John, Carola Schulzke, Anukul Jana, Sankaranarayana Pillai Sarish, Alexander Döring
Publikováno v:
Organometallics. 28:2563-2567
The reaction of 1 equiv of β-diketiminate lithium, LLi·OEt2 {L = HC(CMeNAr)2 (Ar = 2,6-iPr2C6H3), nacnac ligand} with 1 equiv of PbCl2 in THF afforded the β-diketiminate lead(II) chloride (1) as a ...
Autor:
Regine Herbst-Irmer, Selvarajan Nagendran, Sharanappa Nembenna, Sankaranarayana Pillai Sarish, Herbert W. Roesky, Arne Ringe, Jörg Magull, Aritra Pal
Publikováno v:
Inorganic Chemistry. 47:5971-5977
Controlled hydrolysis of strontium amide LSrN(SiMe 3) 2(thf) (L = CH(CMe2,6- i-Pr 2C 6H 3N) 2) ( 1) gave an unprecedented example of a hydrocarbon-soluble strontium hydroxide, [LSr(thf)(mu-OH) 2Sr(thf) 2L] ( 2). In compound 2, the tetrahydrofuran (TH