Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Sandrine Jacquot-Rousseau"'
Autor:
Michael Knorr, Rodolphe Kinghat, Abderrahim Khatyr, Kabula Ciamala, Gérard Schmitt, Sandrine Jacquot-Rousseau, Yoann Rousselin, Marek M. Kubicki
Publikováno v:
Comptes Rendus Chimie
Comptes Rendus Chimie, Elsevier, 2016, 19, pp.320-332. ⟨10.1016/j.crci.2015.09.017⟩
Comptes Rendus Chimie, Elsevier, 2016, 19, pp.320-332. ⟨10.1016/j.crci.2015.09.017⟩
1,3-dipolar cycloaddition of diaryldiazomethanes Ar2C N2 across Cl3C–CH N–CO2Et 1 yields Δ3-1,2,4-triazolines 2. Thermolysis of 2 leads, via transient azomethine ylides 3, to diaryldichloroazabutadienes [Ar(Ar')C N–CH CCl2] 4. Treatment of 4a
Autor:
Gérard Schmitt, Sandrine Jacquot-Rousseau, Estelle Vigier, Michael Knorr, Olivier Blacque, Marek M. Kubicki, Abderrahim Khatyr
Publikováno v:
European Journal of Organic Chemistry. 2006:1555-1562
Treatment of 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene [Cl2C=C(H)-N=CPh2] (1) with excess sodium isopropylthiolate or sodium thiophenolate in DMF yielded the 2-azabutadiene derivatives (RS)2C=C(H)–N=CPh2 (2) (2a R = iPr; 2b R = Ph). Nucleophili
Publikováno v:
ChemInform. 33
Publikováno v:
Scopus-Elsevier
The unexpected formation of a 2H-pyrrole by reaction of potassium cyanide with 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene and the mechanism of this reaction are described and the structures of the product and a trapped intermediate confirmed by X-
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 58:o364-o365
The title compound, C19H15ClN2, is the sole stable product resulting from nucleophilic attack of the sodium salt of pyrrole on 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene. The mechanism of its formation is briefly discussed.