Zobrazeno 1 - 10
of 119
pro vyhledávání: '"Samuel Braverman"'
Publikováno v:
ARKIVOC, Vol 2004, Iss 2, Pp 51-63 (2003)
Externí odkaz:
https://doaj.org/article/bbc643e2ba0e44bba603bb84e715a0ad
Autor:
Yulia Kalendar, Ranjan Jana, Israel Goldberg, Samuel Braverman, Milon Sprecher, M. Cherkinsky
Publikováno v:
Synthesis. 46:119-125
A convenient procedure for the synthesis of novel bis-(1-hydroxymethyl-2-halo-3-hydroxy-1-propylene) selenides has been developed. On oxidation these compounds form novel seleno-spiro compounds and their glutathione peroxidase mimetic activity has be
Autor:
Milon Sprecher, M. Cherkinsky, Yuliya Kalendar, Samuel Braverman, Hugo E. Gottlieb, Arie Gruzman, Ella Meltzer Mats, Israel Goldberg
Publikováno v:
Journal of Physical Organic Chemistry. 26:102-108
The one-pot three-component preparation of novel selenium-containing spiroketals with potential biological activity is described. When in situ prepared selenium dichloride is reacted with either propargyl or homopropargyl alcohols in the presence of
Publikováno v:
Synthesis. 2011:1741-1750
Thirty-five substituted bis(propargyloxy) disulfides were successfully prepared in good to excellent yields, and their reactivity was found to be strongly dependent on the substitution pattern of the reactant. Inter alia they undergo surprising tande
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 186:1251-1254
A convenient method to incorporate selenium into an organic molecule is reported. Selenium halides undergo smooth 1,2-addition to the triple bond of various propargylic alcohols under mild reaction conditions and with complete regio- and stereospecif
Publikováno v:
Journal of Physical Organic Chemistry. 23:1114-1120
A convenient method to incorporate selenium into an organic molecule is reported. Various aspects of the reaction of SeCl2 with propargyl alcohols, i.e., identity of reacting functionality, regiospecificity, and stereospecificity, differ from expecta
Publikováno v:
Recueil des Travaux Chimiques des Pays-Bas. 114:51-60
The synthesis of thiophenes starting from allenyl sulfones, via intermediate formation of α,β-unsaturated sulfines, is described. The allenyl sulfones were synthesized by a [2,3]-sigmatropic rearrangement of appropriately substituted prop-2-ynyl su
Publikováno v:
Tetrahedron. 66:1925-1930
Synthesis and facile rearrangement and cyclization reaction of new dipropargylic disulfides are described. A possible mechanism for these transformations involving an initial double [2,3]-sigmatropic rearrangement to the elusive diallenyl disulfides
Publikováno v:
Synlett. 2007:2663-2666
Symmetrical Z, Z-bis(1-hydroxymethyl-2-chlorovinyl) selenides have been obtained in high yields by regio- and stereo-specific addition of selenium dichloride to propargylic alcohols. Presumably, the hydroxyl group plays an important role in the -regi
Publikováno v:
Tetrahedron Letters. 48:6713-6716
The synthesis and reactivity of diallenic α-disulfones and diallenic sulfinyl sulfones are described. Both types of compound exhibit enhanced reactivity relative to their saturated counterparts, and react spontaneously at low temperature, upon prepa