Zobrazeno 1 - 2
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pro vyhledávání: '"Samir Gopal Bhattacharya"'
Publikováno v:
Journal of Coordination Chemistry. 19:311-320
Thermodynamics and kinetics of 1:1 complexation of iron(III) with benzo- and several ortho-substituted (CH3, NH2, Cl and OH) benzohydroxamic acids (HL) forming FeL2+ have been investigated spectropho-tometrically in aqueous perchloric acid solution.
Publikováno v:
Transition Metal Chemistry. 8:241-243
At elevated temperatures (⩾ 70 °C) the title complex aquates significantly in aqueous acid media, releasing one thiocyanate in the first step, which exhibits no acid dependence. For this spontaneous aquation, the rate constant (kspont.) at 25 °C,