On the Redox Properties of the Dimers of Thiazol-2-ylidenes That Are Relevant for Radical Catalysis

Autor: Ludivine Delfau, Nadhrata Assani, Samantha Nichilo, Jacques Pecaut, Christian Philouze, Julie Broggi, David Martin, Eder Tomás-Mendivil

Publikováno v: ACS Organic & Inorganic Au.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2b11135400f6c0559245895c89490bad
https://doi.org/10.1021/acsorginorgau.3c00008

Critical Assessment of the Reducing Ability of Breslow-type Derivatives and Implications for Carbene-Catalyzed Radical Reactions*

Autor: Eder Tomás-Mendivil, Samantha Nichilo, Julie Broggi, Florian Molton, David C. Martin, Ludivine Delfau

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, In press, ⟨10.1002/anie.202111988⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, In press, ⟨10.1002/anie.202111988⟩

International audience; We report the synthesis of acyl azolium salts stemming from thiazolylidenes C NS , triazolylidenes C TN, mesoionic carbenes C MIC and the generation of their corresponding radicals and enolates, covering about 60 Breslow-type

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c6d7c5c9c33b9342a001f956066e834
https://pubmed.ncbi.nlm.nih.gov/34651408