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pro vyhledávání: '"Sam Myllynen"'
Autor:
Mikael Wasberg, Sam Myllynen
Publikováno v:
Journal of Electroanalytical Chemistry. 661:294-302
Electrochemical, metal-centred partial oxidation of the electrodeposited d8 Ru–Ru bonded chain [Ru0(bpy)(CO)2]n results in high electrical conductivity on the order of 10−1 S cm−1. The partial oxidation of Ru0 is reversible in presence of charg
Autor:
Mikael Wasberg, Sam Myllynen
Publikováno v:
Electrochemistry Communications, Vol 11, Iss 7, Pp 1453-1456 (2009)
High, electrochemically controlled electrical conductivity (0.2–0.3 S cm−1) was measured for the first time for the metal–metal bonded polymeric compound [Ru(bpy)(CO)2]n (bpy = 2,2′-bipyridine). The conductivity depended on the degree of part
Autor:
Mikael Wasberg, Sam Myllynen
Publikováno v:
Journal of Electroanalytical Chemistry. 623:93-101
The dimer [Ru(bpy)(CO) 2 Cl] 2 dissociates in DMSO electrolyte to form free chloride and DMSO-coordinated monocation with an equilibrium constant of ca. 6 × 10 −4 mol dm −3 . Neutral dimer is oxidised with peak potential E p = +0.75 V (vs. Ag/Ag
Publikováno v:
Journal of Electroanalytical Chemistry. 506:115-126
Electroreduction of trans (Cl) and cis (Cl)Ru(L)(CO) 2 Cl 2 (L=bpy=2,2′-bipyridine, dmbpy=4,4′-dimethyl-2,2′-bipyridine) in CH 3 CN and DMSO resulted in electrode-adhering films and the reactions were studied by voltammetry and the electroch