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pro vyhledávání: '"Sam E. Neale"'
Autor:
Thomas X. Gentner, Matthew J. Evans, Alan R. Kennedy, Sam E. Neale, Claire L. McMullin, Martyn P. Coles, Robert E. Mulvey
Publikováno v:
Gentner, T, Evans, M, Kennedy, A, Neale, S, McMullin, C, Coles, M & Mulvey, R 2022, ' Rubidium and caesium aluminyls: synthesis, structures and reactivity in C–H bond activation of benzene ', Chemical communications (Cambridge, England), vol. 58, no. 9, pp. 1390-1393 . https://doi.org/10.1039/D1CC05379E
Expanding knowledge of low valent aluminium chemistry, rubidium and caesium aluminyls are reported to complete the group 1 (Li–Cs) set of metal aluminyls. Both compounds crystallize as a contacted dimeric pair supported by M⋯π(arene) interaction
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f706ed6e0f846c1d9631a00c4e945fd1
https://doi.org/10.1039/d1cc05379e
https://doi.org/10.1039/d1cc05379e
Publikováno v:
Evans, M, Anker, M, McMullin, C, Neale, S & Coles, M 2021, ' Dihydrogen Activation by Lithium-and Sodium-Aluminyls ', Angewandte Chemie-International Edition, vol. 60, no. 41, pp. 22289-22292 . https://doi.org/10.1002/anie.202108934
To date, aluminyl anions have been exclusively isolated as their potassium salts. We report herein the synthesis of the lithium and sodium aluminyls, M2[Al(NONDipp)]2 (M=Li, Na. NONDipp=[O(SiMe2NDipp)2]2−; Dipp=2,6-iPr2C6H3). Both compounds crystal
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::77fbf1469b93ba6c58fd5e77e8f162b2
https://doi.org/10.1002/anie.202108934
https://doi.org/10.1002/anie.202108934