Oxidation of bis-sulfinyl carbanions as the pivot of ionic/radical tandem reactions

Autor: Sophie Beauvière, Catherine Gomez, Jean Philippe Goddard, Louis Fensterbank, Rocio Martinez Mallorquin, Max Malacria, Ilan Marek, Adi Abramovitch, Franck Brebion, Guillaume Vincent, Saloua Cheli

Publikováno v: Comptes Rendus. Chimie
Comptes Rendus. Chimie, 2016, 19 (3), pp.403-411. ⟨10.1016/j.crci.2015.11.012⟩
Comptes Rendus. Chimie, Académie des sciences (Paris), 2016, 19 (3), pp.403-411. ⟨10.1016/j.crci.2015.11.012⟩
Comptes Rendus Chimie
Comptes Rendus Chimie, Elsevier Masson, 2016, 19 (3), pp.403-411. <10.1016/j.crci.2015.11.012>

International audience; [1,4]-additions of various nucleophiles such as lithiated carbamates, alkoxides or ester enolates onto enantiopure alkylidene bis-sulfoxides proceed with high diastereoselectivity. The oxidation of the resulting carbanions wit

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https://hal.science/hal-01397953/file/1-s2.0-S1631074815003240-main.pdf