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pro vyhledávání: '"Sally-Ann Brough"'
Autor:
Chris Hall, Andrew McCamley, Stefan Stahl, Robin N. Perutz, Sally-Ann Brough, Helmut Werner, Ulrich Wecker
Publikováno v:
Journal of Organometallic Chemistry. 504:33-46
The photochemistry of a series of Os(η6-arene) complexes has been investigated in argon, methane and dinitrogen matrices with IR and UV/vis detection. The coordinatively unsaturated complex, Os(η6-C6H3Me3)(CO), may be formed by photolysis of either
Publikováno v:
Organometallics. 12:2933-2941
The ethene complexes CpIr(L)(C2H4) (Cp = 7)1 2345-C5H5, L = PPh3, CO) undergo two competing photochemical reactions in solution: (i) isomerization to the vinyl hydride CpIr(L) (C2H3)H and (ii) dissociation of ethene and insertion into solvent C-H bon