Zobrazeno 1 - 5
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pro vyhledávání: '"Sagiri Watanabe"'
Publikováno v:
The Journal of Organic Chemistry. 83:10762-10769
Chiral macrocyclic receptors 1 with multiple hydrogen-bonding sites in the cavity were synthesized and used as NMR chiral solvating agents (CSAs). The Suzuki–Miyaura cross-coupling reaction gave rapid access to a series of variants 1b–p of unsubs
Publikováno v:
Organic Letters. 19:4070-4073
Among chiral macrocycles 1 synthesized, 1m with the 3,5-bis(trifluoromethyl)phenylethynyl group was the best organocatalyst for the enantioselective synthesis of cyclic carbonates from disubstituted or monosubstituted epoxides and CO2. The X-ray crys
Publikováno v:
Chemical Science
Chiral fluorescent macrocycles enable detection of carboxylate enantiomers using naked eye, which allows for quantitative measurement of the enantiomeric excess with high accuracy (error < 1.6%).
Chiral fluorescent chemosensors featuring macrocy
Chiral fluorescent chemosensors featuring macrocy
Autor:
Pavel Anzenbacher, Tadashi Ema, Nina A. Esipenko, Keiichi Okuda, Tsuyoshi Minami, Sagiri Watanabe, Takayuki Yamasaki
Publikováno v:
Organic letters. 16(5)
Chiral macrocycles featuring sulfonamide and/or amide groups as anion-binding sites were synthesized. X-ray crystal structures and DFT calculations have shown that they adopt different conformations that may lead to unique binding behavior. Indeed, v
Publikováno v:
Organic Letters; Aug2017, Vol. 19 Issue 15, p4070-4073, 4p