Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Safieh N. Yazdi"'
Publikováno v:
Journal of Organometallic Chemistry. 341:63-71
When a solution of biphenylene in trifluoroacetic acid containing mercury(II) trifluoroacetate is photolysed with ultraviolet light, the ESR spectra show the progressive mercuration of the biphenylene radical cation in the β-position. β-Proton hype
Publikováno v:
ChemInform. 19
Publikováno v:
Chemischer Informationsdienst. 15
Autor:
Wang Chang, Peter S. Gregory, Woei Haw Djap, Safieh N. Yazdi, John L. Courtneidge, Alwyn G. Davies
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1541-1542
The e.s.r. spectra of certain tetra-alkylcyclobutadiene radical cations, of the hexamethylcyclopentadience radical cation, and of various polycyclic aromatic radical cations, RH˙+, are observed when the corresponding hydrocarbon cations, RH2+, are p
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :929
The radical cations of various furans, thiophenes, and pyrroles have been generated in fluid solution and characterised by e.s.r. spectroscopy.
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :239
Photolysis of alkylpyrroles in trifluoroacetic acid containing mercury(II) trifluoroacetate, alkylfurans in trifluoroacetic acid, or alkylthiophenes in sulphuric acid, induces oxidation to the corresponding radical cations. The e.s.r. spectra show th
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :570
The e.s.r. spectrum of the pentamethylcyclopentadiene radical cation, Me5C5H·+, is observed when pentamethylcyclopentadiene is photolysed in trifluoroacetic acid.
Publikováno v:
Faraday Discussions of the Chemical Society. 78:49
Methods are reported by which fulvalene and pentalene radical anions and cyclobutadiene, cyclopentadiene and buta-1,3-diene radical cations can be prepared in fluid solution and studied by e.s.r. spectroscopy. These preparations illustrate the genera
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :799
If solutions of hexa-,penta-, tetra-, or tri-alkylcyclopentadienes in trifluoroacetic acid are irradiated with u.v. light, the e.s.r. spectra of the corresponding alkylcyclopentadiene radical cations can be observed. The radical cation Me5C5H+˙ can
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :1192
The mercuration of various arenes is promoted when they are photolysed in trifluoroacetic acid containing mercury(II) trifluoroacetate, and 199Hg hyperfine coupling can be observed in the e.s.r. spectra of the radical cations which are formed.