A US perspective on closing the carbon cycle to defossilize difficult-to-electrify segments of our economy.

Autor: Shaw WJ; Pacific Northwest National Laboratory, Richland, WA, USA. Wendy.shaw@pnnl.gov., Kidder MK; Oak Ridge National Laboratory, Oak Ridge, TN, USA. kidderm@ornl.gov., Bare SR; SLAC National Accelerator Laboratory, Menlo Park, CA, USA. srbare@slac.stanford.edu., Delferro M; Argonne National Laboratory, Lemont, IL, USA. delferro@anl.gov., Morris JR; Ames National Laboratory, Ames, IA, USA. morrisj@ameslab.gov., Toma FM; Lawrence Berkeley National Laboratory, Berkeley, CA, USA. fmtoma@lbl.gov.; Institute of Functional Materials for Sustainability, Helmholtz Zentrum Hereon, Teltow, Brandenburg, Germany. fmtoma@lbl.gov., Senanayake SD; Brookhaven National Laboratory, Upton, NY, USA. ssenanay@bnl.gov., Autrey T; Pacific Northwest National Laboratory, Richland, WA, USA., Biddinger EJ; Department of Chemical Engineering, The City College of New York, New York, NY, USA., Boettcher S; Lawrence Berkeley National Laboratory, Berkeley, CA, USA.; Department of Chemical & Biomolecular Engineering and Department of Chemistry, University of California, Berkeley, Berkeley, CA, USA., Bowden ME; Pacific Northwest National Laboratory, Richland, WA, USA., Britt PF; Oak Ridge National Laboratory, Oak Ridge, TN, USA., Brown RC; Department of Mechanical Engineering, Iowa State University, Ames, IA, USA., Bullock RM; Pacific Northwest National Laboratory, Richland, WA, USA., Chen JG; Brookhaven National Laboratory, Upton, NY, USA.; Department of Chemical Engineering, Columbia University, New York, NY, USA., Daniel C; Argonne National Laboratory, Lemont, IL, USA., Dorhout PK; Vice President for Research, Iowa State University, Ames, IA, USA., Efroymson RA; Oak Ridge National Laboratory, Oak Ridge, TN, USA., Gaffney KJ; SLAC National Accelerator Laboratory, Menlo Park, CA, USA., Gagliardi L; Department of Chemistry, The University of Chicago, Chicago, IL, USA., Harper AS; Pacific Northwest National Laboratory, Richland, WA, USA., Heldebrant DJ; Pacific Northwest National Laboratory, Richland, WA, USA.; Chemical Engineering and Bioengineering, Washington State University, Pullman, WA, USA., Luca OR; Department of Chemistry, University of Colorado Boulder, Boulder, CO, USA., Lyubovsky M; Booz Allen Hamilton, Washington DC, USA., Male JL; Pacific Northwest National Laboratory, Richland, WA, USA.; Biological Systems Engineering Department, Washington State University, Pullman, WA, USA., Miller DJ; Lawrence Berkeley National Laboratory, Berkeley, CA, USA., Prozorov T; Ames National Laboratory, Ames, IA, USA., Rallo R; Pacific Northwest National Laboratory, Richland, WA, USA., Rana R; Department of Chemical Engineering, University of California, Davis, CA, USA., Rioux RM; Department of Chemical Engineering, The Pennsylvania State University, University Park, PA, USA., Sadow AD; Ames National Laboratory, Ames, IA, USA.; Department of Chemistry, Iowa State University, Ames, IA, USA., Schaidle JA; National Renewable Energy Laboratory, Golden, CO, USA., Schulte LA; Department of Natural Resource Ecology and Management, Iowa State University, Ames, IA, USA., Tarpeh WA; Department of Chemical Engineering, Stanford University, Stanford, CA, USA., Vlachos DG; Department of Chemical and Biomolecular Engineering, University of Delaware, Newark, DE, USA., Vogt BD; Department of Chemical Engineering, The Pennsylvania State University, University Park, PA, USA., Weber RS; Pacific Northwest National Laboratory, Richland, WA, USA., Yang JY; Department of Chemistry, University of California Irvine, Irvine, CA, USA., Arenholz E; Pacific Northwest National Laboratory, Richland, WA, USA., Helms BA; Lawrence Berkeley National Laboratory, Berkeley, CA, USA., Huang W; Ames National Laboratory, Ames, IA, USA.; Department of Chemistry, Iowa State University, Ames, IA, USA., Jordahl JL; Department of Natural Resource Ecology and Management, Iowa State University, Ames, IA, USA., Karakaya C; Oak Ridge National Laboratory, Oak Ridge, TN, USA., Kian KC; Independent consultant, Washington DC, USA.; Department of Chemical Engineering, Worcester Polytechnic Institute, Worcester, MA, USA., Kothandaraman J; Pacific Northwest National Laboratory, Richland, WA, USA., Lercher J; Pacific Northwest National Laboratory, Richland, WA, USA.; Department of Chemistry, Technical University of Munich, Munich, Germany., Liu P; Brookhaven National Laboratory, Upton, NY, USA., Malhotra D; Pacific Northwest National Laboratory, Richland, WA, USA., Mueller KT; Pacific Northwest National Laboratory, Richland, WA, USA., O'Brien CP; Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, IN, USA., Palomino RM; BASF Corporation, Iselin, NJ, USA., Qi L; Ames National Laboratory, Ames, IA, USA., Rodriguez JA; Brookhaven National Laboratory, Upton, NY, USA., Rousseau R; Oak Ridge National Laboratory, Oak Ridge, TN, USA., Russell JC; Advanced Research Projects Agency - Energy, Department of Energy, Washington DC, USA., Sarazen ML; Department of Chemical and Biological Engineering, Princeton University, Princeton, NJ, USA., Sholl DS; Oak Ridge National Laboratory, Oak Ridge, TN, USA., Smith EA; Ames National Laboratory, Ames, IA, USA.; Department of Chemistry, Iowa State University, Ames, IA, USA., Stevens MB; SLAC National Accelerator Laboratory, Menlo Park, CA, USA., Surendranath Y; Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA, USA., Tassone CJ; SLAC National Accelerator Laboratory, Menlo Park, CA, USA., Tran B; Pacific Northwest National Laboratory, Richland, WA, USA., Tumas W; National Renewable Energy Laboratory, Golden, CO, USA., Walton KS; School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA.

Publikováno v: Nature reviews. Chemistry [Nat Rev Chem] 2024 May; Vol. 8 (5), pp. 376-400. Date of Electronic Publication: 2024 May 01.

Supported Platinum Nanoparticles Catalyzed Carbon-Carbon Bond Cleavage of Polyolefins: Role of the Oxide Support Acidity.

Autor: Lamb JV; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Lee YH; Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, California 93106, United States., Sun J; Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, California 93106, United States., Byron C; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Uppuluri R; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States., Kennedy RM; Aeternal Upcycling, Inc., Chicago, Illinois 60640, United States., Meng C; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Behera RK; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Wang YY; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Qi L; Chemical and Biological Sciences Division, Ames National Laboratory, Ames, Iowa 50011, United States., Sadow AD; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.; Chemical and Biological Sciences Division, Ames National Laboratory, Ames, Iowa 50011, United States., Huang W; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.; Chemical and Biological Sciences Division, Ames National Laboratory, Ames, Iowa 50011, United States., Ferrandon MS; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Scott SL; Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, California 93106, United States.; Department of Chemical Engineering, University of California, Santa Barbara, Santa Barbara, California 93106, United States., Poeppelmeier KR; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States., Abu-Omar MM; Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, California 93106, United States.; Department of Chemical Engineering, University of California, Santa Barbara, Santa Barbara, California 93106, United States., Delferro M; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.

Publikováno v: ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2024 Mar 06; Vol. 16 (9), pp. 11361-11376. Date of Electronic Publication: 2024 Feb 23.

Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins.

Autor: Tennakoon A; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.; Chemical and Biological Sciences Division, Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States., Wu X; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.; Chemical and Biological Sciences Division, Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States., Meirow M; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States., Howell D; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Willmon J; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Yu J; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Lamb JV; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Delferro M; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Luijten E; Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.; Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.; Department of Engineering Sciences and Applied Mathematics, Northwestern University, Evanston, Illinois 60208, United States.; Department of Physics and Astronomy, Northwestern University, Evanston, Illinois 60208, United States., Huang W; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.; Chemical and Biological Sciences Division, Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States., Sadow AD; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.; Chemical and Biological Sciences Division, Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2023 Aug 16; Vol. 145 (32), pp. 17936-17944. Date of Electronic Publication: 2023 Aug 04.

Zirconium-Catalyzed C-H Alumination of Polyolefins, Paraffins, and Methane.

Autor: Kanbur U; Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States.; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Paterson AL; Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States., Rodriguez J; Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States., Kocen AL; Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States., Yappert R; Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Hackler RA; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Wang YY; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Peters B; Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Delferro M; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States.; Pritzker School of Molecular Engineering, University of Chicago, Chicago, Illinois 60637, United States., LaPointe AM; Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States., Coates GW; Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, United States., Perras FA; Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States., Sadow AD; Ames National Laboratory, Iowa State University, Ames, Iowa 50011, United States.; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2023 Feb 08; Vol. 145 (5), pp. 2901-2910. Date of Electronic Publication: 2023 Jan 25.

Size-Controlled Nanoparticles Embedded in a Mesoporous Architecture Leading to Efficient and Selective Hydrogenolysis of Polyolefins.

Autor: Wu X; US DOE, Ames Laboratory, Iowa State University, Ames, Iowa 50011, United States.; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Tennakoon A; US DOE, Ames Laboratory, Iowa State University, Ames, Iowa 50011, United States.; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Yappert R; Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Esveld M; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Ferrandon MS; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Hackler RA; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., LaPointe AM; Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14583, United States., Heyden A; Department of Chemical Engineering, University of South Carolina, Columbia, South Carolina 29208, United States., Delferro M; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Peters B; Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, United States., Sadow AD; US DOE, Ames Laboratory, Iowa State University, Ames, Iowa 50011, United States.; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States., Huang W; US DOE, Ames Laboratory, Iowa State University, Ames, Iowa 50011, United States.; Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States.

Publikováno v: Journal of the American Chemical Society [J Am Chem Soc] 2022 Mar 30; Vol. 144 (12), pp. 5323-5334. Date of Electronic Publication: 2022 Feb 23.