Electronic Properties, Redox Behavior, and Interactions with H2O2 of pH-Sensitive Hydroxyphenyl-1,2,4-triazole-Based Oxovanadium(V) Complexes

Autor: Browne, WR, Ligtenbarg, AGJ, de Boer, JW, van den Berg, TA, Lutz, M, Spek, AL, Hartl, F, Hage, R, Feringa, BL, Spek, Anthony L., Feringa, Bernard

Publikováno v: Inorganic Chemistry, 45(7), 2903-2916. AMER CHEMICAL SOC
Inorganic Chemistry, 45(7), 2903-2916. American Chemical Society
Inorganic Chemistry, 45, 2903. American Chemical Society

The syntheses and spectroscopic characterization of two 1,2,4-triazole-based oxovanadium(V) complexes are reported: 1(-)[VO(2)L1](-) and 2 [(VOL2)(2)(OMe)(2)] (where H(2)L1 = 3-(2'-hydroxyphenyl)-5-(pyridin-2"-yl)-H-1-1,2,4-triazole, H3L2 = bis-3,5-(

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c8471606b597bbd4b6471ab912d9914
https://hdl.handle.net/11245/1.257065

X-Ray Structure of a Molecular Basket - Origin of Its Poor Binding-Properties

Autor: Martens, Cf, Sijbesma, Rp, Gebbink, Rjmk, Spek, Al, Roeland Nolte

Publikováno v: Recueil des Travaux Chimiques des Pays-Bas, 112, 6, pp. 400-403
Recueil des Travaux Chimiques des Pays-Bas, 112, 400-403. Elsevier Science bv
ResearcherID

Contains fulltext : 10371.pdf (Publisher’s version ) (Open Access)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::10b48ee017d707ac85fb94976db4924a
https://hdl.handle.net/2066/16436

Catalytic enantioselective Michael addition reactions of alpha-nitroesters to alpha,beta-unsaturated ketones

Autor: Keller, E, Veldman, N, Spek, AL, Feringa, BL

Publikováno v: Tetrahedron-Asymmetry, 8(20), 3403-3413. PERGAMON-ELSEVIER SCIENCE LTD

Enantioselective Michael additions of alpha-nitroesters 2a-d with alpha,beta-unsaturated ketones were carried out in the presence of a catalytic amount of chiral Al-Li-(R,R')-2,2'-dihydroxy-1,1'-binaphthyl ('AlLiBINOL') complex prepared in situ from

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=narcis______::89f3d912692b6d0433afa221af67c47d
https://research.rug.nl/en/publications/6df52b9c-50b2-4a24-9b00-713a26bb6213

Bis(tetramethylcyclopentadienyl)titanium chemistry. Molecular structures of [(C(5)HMe(4))(mu-eta(1): eta(5)-C(5)Me(4))Ti](2) and [(C(5)HMe(4))(2)Ti]N-2(2)

Autor: deWolf, JM, Blaauw, R, Meetsma, A, Teuben, JH, Gyepes, R, Varga, [No Value], Mach, K, Veldman, N, Spek, AL

Publikováno v: Organometallics, 15(23), 4977-4983. AMER CHEMICAL SOC INC

Thermolysis of bis(tetramethylcyclopentadienyl)-stabilized titanium(III) compounds (C(5)HMe(4))(2)TiR (R = Me (2), Ph (3)) yields, in marked contrast with the bis(pentamethylcyclopentadienyl) analog, the dimeric product [(C(5)HMe(4))(mu-eta(1):eta(5)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=narcis______::c44e417b86c4aacfcf56534a12ae562c
https://research.rug.nl/en/publications/fd0838d0-f820-49b6-92e6-58521f4dffbb

MECHANISM OF THE CONTROLLED HYDROLYSIS OF (NPCL2)(2)NSOCL - CRYSTAL AND MOLECULAR-STRUCTURE OF [KC12H24O6](+)[NHPO2NPCL2NSOCL](-)

Autor: WINTER, H, MEETSMA, A, VANDEGRAMPEL, JC, SPEK, AL

Publikováno v: Heteroatom chemistry, 5(4), 343-348

The reaction mechanism of controlled hydrolysis of the inorganic ring system (NPCl2)(2)NSOCl in the presence of KCl and 18-crown-6 has been revised and is explained from steric constraints rather than from electronic considerations. The X-ray structu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=narcis______::6b872a176b0d1b7f8e52412a6bbcc847
https://research.rug.nl/en/publications/8f620473-ab4c-4647-8a49-f9a79c22fa9a