Zobrazeno 1 - 10
of 145
pro vyhledávání: '"SHIN, TAKEMOTO"'
Autor:
Shin Takemoto, Hiroyuki Matsuzaka
Publikováno v:
Journal of Synthetic Organic Chemistry, Japan. 79:1136-1143
Publikováno v:
Journal of the American Chemical Society. 143:16105-16112
The formation of linear hydrocarbon chains by sequential coupling of C1 units on the metal surface is the central part of the Fischer-Tropsch (F-T) synthesis. Organometallic complexes have provided numerous models of relevant individual C-C coupling
Publikováno v:
ACS Catalysis. 11:7460-7466
Autor:
Hana Ishii, Akira Teramoto, Masahiro Yamaguchi, Masayuki Tsujita, Hiroyuki Matsuzaka, Daiki Ozeki, Shin Takemoto
Publikováno v:
Organometallics. 38:4298-4306
The complex salt [CpRu(η6-C10H8)][(CpRu)2(μ-Cl)3] ([1][2]) was synthesized and found to be a useful CpRuCl synthon. The ions [1]+ and [2]− cleanly comproportionate into monomeric CpRuCl(L)2 complex...
Publikováno v:
Organometallics. 37:1591-1597
The diiridium(I) μ-hydroxo complex [Ir(μ-OH)(cod)]2 (1; cod = 1,5-cyclooctadiene) readily reacted with aqueous NaOH in DMSO-d6 or NaN(SiMe3)2 in THF to give the anionic trinuclear iridium oxo complex Na[{Ir(cod)}3(μ3-O)2] (2) in high yield. Comple
Autor:
Hiroyuki Matsuzaka, Shin Takemoto
Publikováno v:
Tetrahedron Letters. 59:697-703
The π-complexation of an arene to a transition metal center delivers many useful reactivities to the arene moiety. Although synthetic methodologies that take advantage of such π-coordination have mostly been developed as stoichiometric processes, t
Publikováno v:
Organometallics. 36:3686-3691
Deprotonation of the diruthenium μ-methylidyne complex [(Cp*Ru)2(μ-NtBu)(μ-CH)][BF4] (Cp* = η5-C5Me5) with 2 equiv of KN(SiMe3)2 in the presence of CuCN, AgOTf, or AuCl(SMe2) afforded the trigonal planar bridging carbido complexes [(Cp*Ru)2(μ-Nt
Publikováno v:
Journal of the American Chemical Society; 10/6/2021, Vol. 143 Issue 39, p16105-16112, 8p
Publikováno v:
Journal of Organometallic Chemistry. 812:158-166
The diruthenium imido complex [(Cp*Ru)2(μ-NPh)(μ-CH2)] (1; Cp* = η5-C5Me5) reacts with a variety of Bronsted acidic element-hydrogen bonds to give amido complexes of the type [(Cp*Ru)2(μ-NHPh)(X)(μ-CH2)]. Single-crystal X-ray structures are repo
Publikováno v:
Journal of Organometallic Chemistry. 808:97-103
The reaction of [Cp*Ru(μ-OEt)]2 (1) with sulfonamides affords terminal sulfonamido complexes via alkoxo-sulfonamido exchange and either symmetrical or unsymmetrical cleavage of the dimeric structure. The neutral phosphine-ligated monomeric complexes