Zobrazeno 1 - 10
of 127
pro vyhledávání: '"S.M. Baturin"'
Autor:
Vera P. Lodygina, A. I. Kuzaev, S.M. Baturin, V. V. Komratova, Elmira R. Badamshina, Yu.A. Ol'khov, G. A. Gorbushina, V. A. Grigorieva
Publikováno v:
International Journal of Polymeric Materials. 19:117-125
The reactions of PCT and CPCT of aliphatic isocyanates in the presence of catalysts HBSO and CN-DMSO were found to obey the first-order law. The observed rate constants at various temperatures and catalyst concentrations, the activation energy were d
Publikováno v:
Polymer Science U.S.S.R.. 32:1175-1180
The kinetics of urethane formation on reaction of oligobutadienediols with 2,4-toluylene diisocyanate at an [NCO]:[OH] ratio 2:1 (prepolymer synthesis) is studied, and it is shown that a change in the reactivity of oligobutadienediols of different MM
Publikováno v:
Polymer Science U.S.S.R.. 32:1237-1241
The cyclotrimerization of 1,6-hexamethylenediisocyanate has been investigated in the presence of bis(tributyl tin)oxide without a solvent in the 353–393 K range by microcalorimetry, IR spectroscopy and gel permeation chromatography. The polycyclotr
Publikováno v:
Polymer Science U.S.S.R.. 27:1276-1283
GPC and IR spectroscopy have been employed to investigate the properties of the sol fractions of polyether urethane elastomers from catalytic polymerization. The characteristics of the MMD of the sol fractions have been determined and their dependenc
Publikováno v:
Polymer Science U.S.S.R.. 28:389-396
Specific intermolecular interactions in mixtures containing oligobutadienyl urethane and oligooxyoctene triol have been studied by microcalorimetry and IR spectroscopy. Complex hydrogen-bonded associates are formed in this mixture, which involve uret
Publikováno v:
Polymer Science U.S.S.R.. 18:2808-2814
Heat stimulated depolarization (HSD) has been used to study the relaxation processes in crosslinked polyurethane (PU) elastomers. The activation parameters of dipole relaxation have been determined in the glass transition range. The main contribution
Publikováno v:
Polymer Science U.S.S.R.. 20:230-238
The use of tin dibutyl dilaurate for the preparation of crosslinked polyether urethanes changes the rules of thermal decomposition (reduces the activation energy and pre-exponential factor, changes the order of the reaction) and weakens the dependenc
Publikováno v:
Polymer Science U.S.S.R.. 20:2412-2417
Using a system incorporating a copolymer of tetrahydrofuran and propylene oxide, 1,4-butanediol, 1,1,1-trimethylolpropane and 2,4-toluylenedi-isocyanate, an analysis was made of the possible use of critical conditions of gel formation and the concent
Publikováno v:
Polymer Science U.S.S.R.. 26:1880-1888
The influence of plasticizers of various types affecting the physico-chemical and mechanical properties of polyurethane elastomers has been investigated for compositions comprising the copolymer of tetrahydrofuran and propylene oxide (PO), trimethylo
Publikováno v:
Polymer Science U.S.S.R.. 20:309-313
The effect of molecular weight and polydispersity on the relaxational behaviour of linear poly(oxypropylene glycols) (POPGS) has been studied by pulse NMR spectroscopy. The length of the kinetic segment of the oligomer was determined. It is suggested