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Homolytic addition of benzyl bromide to unsaturated compounds in conditions of metal-complex initiation

Autor: S. I. Gapusenko, S. V. Vitt, A. B. Terent'ev, T. T. Vasil'eva

Publikováno v: Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1841-1845

Radical addition of benzyl bromide to unsaturated compounds containing substituents of a different polar nature, CH2=CHX (X=C4H9, SiMe3, CF3, CO2Me, CN, H), was conducted in the presence of the Fe(CO)5 + DMF (HMPA) system. Adducts were obtained and t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::843c51d5cca009ca3c140f912a36fb26
https://doi.org/10.1007/bf00863820

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Relative kinetics of the radical addition of benzyl bromide to unsaturated compounds

Autor: S. I. Gapusenko, A. B. Terent'ev, S. V. Vitt, T. T. Vasil'eva

Publikováno v: Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1567-1571

The relative rate constants of the addition of the C6H5CH2 radical to unsaturated compounds CH2=CHX (X = C4H9, SiMe3, CF3, CO2Me, CN) were determined under the conditions of initiation by the Fe(CO)5 + DMF system or by benzoyl peroxide. Depending on

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::1963bb4834240e94244cecfafda730f3
https://doi.org/10.1007/bf00863574

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