Zobrazeno 1 - 6
of 6
pro vyhledávání: '"S. V. Kalcheva"'
Publikováno v:
Electrochimica Acta. 108:540-546
The initial steps of sodium borohydride oxidation are studied at PtAu alloy electrodes of Au bulk content of 20, 40, 60 and 80 at.%. Linear sweep voltammetry is applied in 0.01 M NaBH 4 in 1.00 M NaOH varying the scan rate applied. The experiments ar
Publikováno v:
Journal of Electroanalytical Chemistry. 638:275-279
Surface oxides on a Pt–Au alloy in 0.05 M KOH are formed potentiostatically at potentials, varying between 2.00 V and 2.50 V for polarization times, tp, up to 1000 s at temperature values in the range from 293 K to 308 K. This procedure results in
Kinetic and mechanistic evaluation of tetrahydroborate ion electro-oxidation at polycrystalline gold
Publikováno v:
Electrochimica Acta. 54:7236-7241
The anodic oxidation of tetrahydroborate ion is studied in NaOH at stationary and rotating polycrystalline Au disk electrodes. Linear sweep and cyclic voltammetry are applied varying the scan and rotation rate from 0.005 to 51.200 V s −1 and from 5
Autor:
Jie Zhang, Anand I. Bhatt, Philip I. Iotov, Christopher R. Strauss, Douglas R. MacFarlane, S. V. Kalcheva, Alan M. Bond, Janet L. Scott
Publikováno v:
Green Chem.. 8:161-171
Ionic liquids are frequently advocated as green media for electrochemical studies. However, they are non-volatile and hence difficult to purify or recover. In this paper the electrochemical behaviour of a ‘distillable’ room temperature ionic liqu
Autor:
P I Iotov, S. V. Kalcheva
Publikováno v:
Gold Bulletin. 34:95-103
The general behaviour of potentiostatically grown gold oxide films during the oxidation of phenol in basic solutions has been studied using cyclic voltammetry. No catalytic activity is observed and phenol oxidation is prevented when the oxide film co
Autor:
P.I. Iotov, S. V. Kalcheva
Publikováno v:
Journal of Electroanalytical Chemistry. 442:19-26
The electrochemical oxidation of phenol was investigated at a platinum/gold (60/40 at.%) alloy electrode in a 0.5 M H2SO4 aqueous solution at 308.7 K by cyclic voltammetry. Comparative studies were carried out by using platinum and gold electrodes un