Zobrazeno 1 - 9
of 9
pro vyhledávání: '"S. T. E. Mesher"'
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 53:681-685
The crystal structures of trans-[2,3-bis(methylthio)hexane-S,S']dichlorozinc(II), [ZnCl2(C8H18S2)], trans-[1,2-bis(methylthio)cyclohexane-S,S']dichlorozinc(II), [ZnCl2(C8H16S2)], and cis-[1,2-bis(methylthio)-3,5-cycloheptadiene-S,S']dichlorozinc(II),
Publikováno v:
Catalysis Letters. 48:79-82
Direct introduction of -SCH3 groups into activated aromatic and hetero aromatic compounds has been achieved by reaction with dimethyldisulfide over a MnCl2-promoted K-10 montmorillonite. Unlike ZnCl2/K-10, the Mn- promoted clay appears to promote rea
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 114:99-108
A method for the direct thioalkylation of thiophene (1) and benzo[b]thiophene (7) by reaction of either heterocycle with an alkyldisulfide using a ZnCl2-modified montmorillonite clay catalyst is described. The clay-catalyzed reaction of 1 with excess
Autor:
Peter D. Clark, S. T. E. Mesher
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 105:157-162
Benzylation of benzo[b]thiophene (1) with benzyl chloride catalyzed by metal-doped K-10 montmoril-lonite clays is described. Whereas ZnQ2 dissolved in either nitromethane or nitrobenzene solution promoted benzylation of (1) only very slowly and resul
Publikováno v:
Catalysis Letters. 47:73-75
A mild method for 1,2-addition of alkyl disulfides to alkenes and conjugated polyenes catalysed by MClx-promoted montmorillonite clays is reported. Alkenes undergo 1,2-trans addition affording MClx-complexed derivatives, which are readily converted t
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 52:1503-1505
The crystals of the title compound, C 9 H 4 S 4 , are composed of essentially planar molecules separated by normal van der Waals distances, with S=C and S-C sp2 (mean) bond distances of 1.641(7) and 1.741 (11) A, respectively.
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 52:1248-1250
Crystals of the title compound, C12H14S5, are composed of independent molecules separated by normal van der Waals distances. The benzothiophene moiety is essentially planar and substituted by four methylthio groups, two of which, those at positions 2
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 52:905-907
The structure of the title compound, diethyl benzo[b]-thiophene-2,3-disulfinate, C 12 H 14 O 4 S 3 , is composed of an essentially planar benzothiophene moiety containing two ethylsulfonyl groups which are oriented in opposite directions. The mean va
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 95:441-443
Regioselective benzylation of thiophene and benzothiophene using benzyl chloride and a ZnCl2-promoted montmorillonite catalyst is described. An improved process for the cyclization of (arylthio)acetaldehyde dialkyl acetals to benzothiophenes using th