The Staudinger reaction of platinum(II)- and palladium(II)-coordinated 2-(azidomethyl) phenyl isocyanide.X-ray structure of trans [PtCl(CN(H)C6H4-2-2 CH2N(H))(PpH3)2[BF4]

Autor: M. Basato 1, F. Benetollo 2, G. Facchin 3, Rino A. Michelin 4, M. Mozzon 4, S. Pugliese 4, P. Sgarbossa 4, S. Mazzega Sbovata 4, A. Tassan 4

Publikováno v: Journal of organometallic chemistry
689 (2004): 454–462.
info:cnr-pdr/source/autori:M. Basato 1, F. Benetollo 2, G. Facchin 3, Rino A. Michelin 4, M. Mozzon 4, S. Pugliese 4, P. Sgarbossa 4, S. Mazzega Sbovata 4, A. Tassan 4/titolo:The Staudinger reaction of platinum(II)-and palladium(II)-coordinated 2-(azidomethyl) phenyl isocyanide.X-ray structure of trans [PtCl(CN(H)C6H4-2-2 CH2N(H))(PpH3)2[BF4]/doi:/rivista:Journal of organometallic chemistry (Print)/anno:2004/pagina_da:454/pagina_a:462/intervallo_pagine:454–462/volume:689

2-(Azidomethyl)phenyl isocyanide, 2-(CH2N3)C6H4NBC (AziNC), coordinates to some cationic Pt(II) and Pd(II) species to afford isocyanide complexes of the type trans-[MCl(AziNC)(PPh3)2][BF4] (M=Pt, l; Pd, 2). AziNC is coordinated also in some neutral P

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http://www.cnr.it/prodotto/i/18370