Zobrazeno 1 - 10
of 11
pro vyhledávání: '"S. P. Ananthavel"'
Publikováno v:
The Journal of Chemical Physics. 116:1920-1929
We report the formation of heterogeneous OCS–water cluster anions [(OCS)n(H2O)k]− (n⩾1,n+k⩾2), of which OCS−⋅H2O is the most interesting species in view of the near absence of unhydrated OCS− in the same ion source. The presence of OCS
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fb7ad3c9d5b921fc65a97f11ae877f35
https://doi.org/10.1063/1.1433001
https://doi.org/10.1063/1.1433001
Publikováno v:
The Journal of Physical Chemistry A. 102:532-536
UVPES studies and ab initio and DFT computations have been done on the benzene···ICl complex; electron spectral data and computed orbital energies show that donor orbitals are stabilized and acceptor orbitals are destabilized due to complexation.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9c5936b0bfd9183f7048f3c85e5a5aa7
https://doi.org/10.1021/jp972301+
https://doi.org/10.1021/jp972301+
Autor:
M.S. Hegde, S. P. Ananthavel
Publikováno v:
The Journal of Physical Chemistry A. 101:1680-1683
Electron states of 1:2 addition compounds of TiCl4 with diethyl ether and diethyl sulfide in the vapor phase have been studied by HeI photoelectron (UVPES) and electron energy loss spectroscopies (EELS). The peaks in the photoelectron spectra of the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e10cd38e566d5f5acba557abd70b5520
https://doi.org/10.1021/jp962651g
https://doi.org/10.1021/jp962651g
Autor:
Ponnambalam Venuvanalingam, S. P. Ananthavel, Jayaraman Chandrasekhar, Salai Cheettu Ammal, M.S. Hegde
Publikováno v:
Chemical Physics Letters. 248:153-157
The charge-transfer complexes of I-2 with the n-donors diethyl ether and diethyl sulfide were studied at the Hartree-Fock and MP2 levels. The structures were fully optimized using the 3-21G((*)) basis set as well as with effective core potentials. Th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3eb01084bd79a62615430b7497170b46
https://doi.org/10.1016/0009-2614(95)01324-5
https://doi.org/10.1016/0009-2614(95)01324-5
Autor:
Ponnambalam Venuvanalingam, Salai Cheettu Ammal, Jayaraman Chandrasekhar, S. P. Ananthavel, M.S. Hegde
Publikováno v:
Chemical Physics Letters. 228:431-435
He I photoelectron spectra of gas-phase complexes formed by $Br_2$ with diethyl ether and diethyl sulphide have been studied and interpreted using ab initio MO calculations. The key spectral features are assigned to the highest occupied molecular orb
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::505e0a723187cea3ab1686b432bf858b
https://doi.org/10.1016/0009-2614(94)00964-3
https://doi.org/10.1016/0009-2614(94)00964-3
Publikováno v:
Chemical Physics Letters. 217:101-104
Electron states of the benzene...HCl complex have been studied by UV photoelectron spectroscopy. Two vertical ionization energies of the complex at 10.84 and 12.10 eV have been assigned to $\pi$ $C_6H_6$ and $n_{C1}$, orbitals, respectively. While th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b96c6161a5509a3a7722b9cb4fa259e0
https://doi.org/10.1016/0009-2614(93)e1352-h
https://doi.org/10.1016/0009-2614(93)e1352-h
Publikováno v:
Thin Solid Films. :357-359
The electron transmission through thin organic films was investigated in order to reveal the effect of the chemical nature of the molecules composing the thin organic layer and the role of the three-dimensional structure of the film on the electron t
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::730cdcb684b8ed2f42242d613ba1f55f
https://doi.org/10.1016/s0040-6090(98)00669-5
https://doi.org/10.1016/s0040-6090(98)00669-5
Publikováno v:
The Journal of Chemical Physics. 107:1288-1290
In this work we probe the effect of the three dimensional structure of the medium on the efficiency of electron transmission (ET) through it, and demonstrate that all three dimensions are playing a crucial role in the ET through thin films. By produc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::96c2f21357b02b08d8f5485ecd4e2c98
https://doi.org/10.1063/1.474476
https://doi.org/10.1063/1.474476
Publikováno v:
Science (New York, N.Y.). 283(5403)
Electron transmission experiments demonstrate a large asymmetry in the scattering probability of polarized electrons by thin organized films of chiral molecules. This large asymmetry results from the interaction of the electron's wavefunction with ma
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::32c54c1b8b09739e18f39664cebca311
https://pubmed.ncbi.nlm.nih.gov/9933157
https://pubmed.ncbi.nlm.nih.gov/9933157
Autor:
S. P. Ananthavel, M. S. Hegde
Publikováno v:
The Journal of Chemical Physics. 105:4395-4396
HeI photoelectron spectrum of weakly bonded π‐donor complex of benzene with Br2 is obtained. Benzene orbitals are shifted to higher binding energy by 0.25 eV and the bromine orbitals to lower binding energy by about 0.5 eV due to the complex forma
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::481c816e2a6224adfb537e8796f7dcc8
https://doi.org/10.1063/1.472258
https://doi.org/10.1063/1.472258