Zobrazeno 1 - 5
of 5
pro vyhledávání: '"S. N. Shagabutdinova"'
Publikováno v:
Тонкие химические технологии, Vol 2, Iss 3, Pp 29-35 (2007)
The complexation in the system Rh(III) – H2SO4 – H2O at the room temperature in the dilute sulfuric acid has been studied by 103Rh and 17O NMR. The most stable species in solutions are [Rh2(μ-SO4)2(H2O)8] 2+ and [Rh2(μ-OH)(μ-SO4)(H2O)8] 3+; we
Externí odkaz:
https://doaj.org/article/a1e720f9be834b1ca78aff90e6dfcab1
Publikováno v:
Russian Journal of Inorganic Chemistry. 54:1290-1295
Nitration of sulfate complexes of rhodium has been investigated by NMR 103Rh, 14N, 15N, and 17O NMR. At high pH, [Rh(NO2)6]3−, dimer [Rh2(μ-OH)2(NO2)8]4−, and trimer [Rh3(μ-OH)4(OH)(NO2)9]5− are the dominant species in solutions.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::abbe280f95d4bffd1390c65e77696a0b
https://doi.org/10.1134/s003602360908018x
https://doi.org/10.1134/s003602360908018x
Publikováno v:
Russian Journal of Coordination Chemistry. 34:917-923
Solid-state rhodium(III) sulfates and their aqueous solutions were examined by IR and electronic absorption spectroscopy, thermogravimetry, X-ray powder diffraction analysis, and 103Rh and 17O NMR spectroscopy. A study of the spontaneous aquation of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fe737b4c33c05853e26914febb430651
https://doi.org/10.1134/s1070328408120087
https://doi.org/10.1134/s1070328408120087
Publikováno v:
Russian Journal of Coordination Chemistry. 33:140-144
The processes of aquation of Rh(III) complexes in the presence of BaCl2 and Ba(ClO4)2 were studied by the 103RH and 17O NMR methods. In the first case, the final products were found to be the monomeric aqua chloride complexes, while in the second cas
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e3765df7ddbcb23537b31a71f95382ae
https://doi.org/10.1134/s1070328407020121
https://doi.org/10.1134/s1070328407020121
Publikováno v:
Russian Journal of Coordination Chemistry. 33:136-139
The formation of rhodium(III) sulfate complexes under moderately rigorous temperature conditions was studied by 103Rh and 17O NMR spectroscopy. The complexes [Rh2(μ-SO4)2(H2O)8]2+, [Rh2(*μ-SO4)(H2O)8]4+, and [Rh3(μ-SO4)3(μ-OH)(H2O)10]2+ were foun
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d9eaef74817ab3c0b17da460cecb31e0
https://doi.org/10.1134/s107032840702011x
https://doi.org/10.1134/s107032840702011x