Zobrazeno 1 - 10
of 19
pro vyhledávání: '"S. N. Nikol'skii"'
Publikováno v:
Russian Journal of Physical Chemistry B. 12:28-35
The strings formed in the solutions of trifluoroacetylated amino alcohols in cyclohexane were studied. It was found that microscopic strings with the diameter d ∼ 1 μm were woven from tightly coupled rigid submicroscopic strings with the diameter
Autor:
D. S. Gerasimov, Ya. A. Litvin, Alexander N. Shchegolikhin, A. D. Rogozin, S. N. Nikol’skii, M. G. Mikhaleva, Vsevolod A. Tverdislov, Dmitry V. Zlenko, Sergey V. Stovbun, V. P. Mel’nikov
Publikováno v:
Russian Journal of Physical Chemistry B. 10:245-259
The physical mechanisms responsible for the kinetics of nitration of cellulose raw materials of different origin have been studied. It has been shown that the main nitration rate-limiting factor is the speed of untwisting of supercoiled cellulose fib
Autor:
S. N. Nikol’skii, V. F. Ivanov, A. N. Shcherban, Svetlana I. Kuzina, I. A. Shilova, A. I. Mikhailov
Publikováno v:
High Energy Chemistry. 47:192-197
Radiolysis of plant biomass with doses of 200–300 kGy prior to dispersing by chemimechanical methods increases the yield of nanocellulose from cellulosic feedstock by more than a factor of two. Another advantage of radiation pretreatment of initial
Publikováno v:
Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1559-1562
The kinetics of protonation of pseudoephedrine by 3,6-di-tert-butyl-2-hydroxyphenoxyl have been analyzed by the ESR technique. It was shown that protolysis of the radical produced closed ionic pairs with the pseudoephedrine cation in a dimer state.
Publikováno v:
Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:1563-1566
The effect of the viscosity of a toluene solution, with addition of Vaseline oil, on the kinetics of proton transfer from 3,6-di-tert-butyl-2-hydroxyphenoxyl to triethylamine was analyzed by the ESR technique. Activation barriers of the reaction do n
Autor:
A. I. Prokof'ev, S. N. Nikol'skii, Sh. S. Tul'baev, Z. M. Muldakhmetov, A. S. Masalimov, I. B. Bakeev
Publikováno v:
Theoretical and Experimental Chemistry. 27:163-167
Kinetic and thermodynamic parameters of the reversible reaction of proton transfer between 3,6-di-tert-butyl-2-hydroxyphenoxyl and N-methyl-4-piperidone have been investigated by means of ESB. It has been found that proton transfer from the semiquino
Publikováno v:
Theoretical and Experimental Chemistry. 27:220-224
Fast nondegenerate tautomeric transitions in the substituted ortho-hydroxy-phenoxy radical 4-triphenylmethyl-6-tert-butyl-3-chloro-2-hydroxyphenoxyl were detected by the ESR method. The kinetic and thermodynamic parameters of hydrogenotropy were dete
Publikováno v:
Theoretical and Experimental Chemistry. 27:168-172
A study has been made of the influence of solvation factors on the kinetics and mechanism of cationotropism in ion pairs of certain semiquinone anion radicals with ammonium cations. It has been shown that the medium influences the magnetic resonance
Publikováno v:
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:53-57
The kinetic parameters of the fast reversible reaction of proton transfer between paramagnetic proton donors: 3,6-di-tert-butyl-2-hydroxyphenoxyl, 4,6-di-tert-butyl-3-chloro-2-hydroxyphenoxyl, 4-triphenylmethyl-6-tert-butyl-3-chloro-2-hydroxyphenoxyl
Publikováno v:
Soviet Atomic Energy. 47:851-853
The total neutron cross section of /sup 145/Nd are measured in the energy range from 0.02 to 350 ev. The values of the resonance parameters and the energy dependence of the total cross section are important for the design and description of processes