Zobrazeno 1 - 10
of 48
pro vyhledávání: '"S. K. Vasisht"'
Publikováno v:
Journal of Organometallic Chemistry. 694:2252-2257
SnCl 4 acts primarily as an oxidant and oxidizes monolithium bis(trimethylsilyl) hydrazide 1 to mainly bis(trimethylsilyl)amine, BSA and tris(trimethylsilyl)hydrazine, TrSH and itself get reduced to SnCl 2 . Similarly, reaction of SnCl 4 with dilithi
Publikováno v:
Journal of Organometallic Chemistry. 690:1507-1510
Lithium 1,2-bis(trimethylsilyl)hydrazine ( 1a ) reacts with Me 3 SnCl, Et 3 SnBr and Bu 3 SnCl to form bis(trimethylsilyl)(trimethylstannyl)hydrazine ( 2a ), (triethylstannyl)bis(trimethyl silyl)hydrazine ( 2b ) and (tributylstannyl)bis(trimethylsily
Publikováno v:
Zeitschrift f�r anorganische und allgemeine Chemie. 630:1823-1828
The disilyne R**Si≡SiR** (R** = SiMe(SitBu3)2), prepared as the first isolable and realtively stable silicon compound with a SiSi triple bond two years ago by dehalogenation of trans-R**ClSi=SiClR** with LiC10H8 in thf at -78 °C (calc.: Si≡Si di
Publikováno v:
Journal of Organometallic Chemistry. 540:51-54
Sodium bis(trimethylstannyl)amide NaN(SnMe3)2, isolated by the reaction of trimethylstannyldiethylamine with sodium amide, reacts with tris(trimethylsilyl)hydrazino—dichloro-phosphine to form bis(trimethylsilyl)bis(trimethylstannyl)-2-phospha-2-tet
Autor:
S. K. Vasisht, Kavita Bandhu
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 126:101-110
Pentakis(trimethylsilyl)-3-phospha-2-pentazene (Me3Si)2N-N(SiMe3)-P=N-N(SiMe3)2 (1) reacts with Me3COH to form oxidative addition products, the partially desilylated [bis(trimethylsilyl) hydrazino][bis(trimethylsilyl)hydrzono](t-butoxy)phosphorane (2
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 107:189-195
Heteroatom incorporated pentazenes, pentakis(trimethylsilyl)-3-phospha-2-pentazene (Me3Si)2N—N(SiMe2)-P=N—N(SiMe3)2 and pentakis(trimethylsilyl)-3-arsa-2-pentanzene (Me3Si)2N—N(SiMe3)—As=N—N(SiMe3)2 have been isolated by the reaction of [tr
Autor:
S.‐K. Vasisht, N. Wiberg
Publikováno v:
ChemInform. 22
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 47:349-355
Lithylated bis(trimethylsilyl)hydrazines, Li2N2(SiMe3)2 and LiH N2(SiMe3)2 react with (Me3Si)2NECI2 (E ˭ P or As) to form hetero atom incorporated tetrazenes, 1,3.4,4-tetrakis(trimethyIsilyl)-2-phospha-I-tetrazene (Me3Si)2N‒ N(SiMe3)‒ P˭NSiMe3
Autor:
K. U. Johal, S. K. Vasisht
Publikováno v:
Main Group Metal Chemistry, Vol 22, Iss 4, Pp 247-252 (1999)