Zobrazeno 1 - 10
of 46
pro vyhledávání: '"S. Hilgard"'
Publikováno v:
Carbohydrate Research. 343:2789-2796
The crystal structures of a complete series of configurational isomers of 2,3-epimino and 3,4-epimino derivatives of 1,6-anhydro-β-D-hexopyranoses were determined by single-crystal X-ray analysis. The structures exhibited conformational rigidity wit
Publikováno v:
Collection of Czechoslovak Chemical Communications. 68:751-778
Anhydrides of 3β,28-diacetoxy-21,22-secolup-18-ene-21,22-dioic acid (1) and (19R)-3β,28-diacetoxy-18β,19-epoxy-21,22-secolupane-21,22-dioic acid (11) undergo alkaline hydrolysis yielding the corresponding dicarboxylic acids. Depending on reaction
Publikováno v:
Collection of Czechoslovak Chemical Communications. 60:619-635
A series of derivatives with various oxygen functionalities in positions 17,22a or 19,20 was prepared from diene I and olefin XVI by addition and oxidation reactions. The structure of the obtained compounds was confirmed by 1H NMR, 13C NMR and IR spe
Publikováno v:
Collection of Czechoslovak Chemical Communications. 58:1675-1691
The triterpenoid α-diketone with oxabicyclo[2.2.2]octane system in the ring E (3β-acetoxy-21,22-dioxo-18α,19βH-ursan-28,20β-olide (I)) gives isopropylidenedioxy derivative II and dimeric compounds V and IX when submitted to chromatography on sil
Publikováno v:
ChemInform. 22
Publikováno v:
Collection of Czechoslovak Chemical Communications. 56:966-972
Infrared spectra of triterpenoid 19β,28-epoxy-18α-oleanane 3-ketones I - VI in the region of carbonyl stretching frequencies have been studied. Comparison of the spectra of crystals with those of solutions in various solvents, together with compari
Publikováno v:
ChemInform. 34
Publikováno v:
Collection of Czechoslovak Chemical Communications. 54:737-750
The crystal structure of allobetulone (I) has been determined. The compound is orthorhombic, P212121, a = 14.824(4), b = 25.701(7), c = 6.545(2) *A, Z = 4, R = 0.050 for 2 303 observed reflections. The rings B, C, D and E assume chair conformation, t
Publikováno v:
Collection of Czechoslovak Chemical Communications. 40:1801-1810
Publikováno v:
Collection of Czechoslovak Chemical Communications. 41:770-779