Molecular Structure–(Thermo)electric Property Relationships in Single-Molecule Junctions and Comparisons with Single- and Multiple-Parameter Models

Autor: Laura Rincón-García, Richard J. Nichols, Oday A. Al-Owaedi, Nicolás Agraït, Pablo Bastante, Paul J. Low, Gabino Rubio-Bollinger, Masnun Naher, David C. Milan, Inco J. Planje, Colin J. Lambert, Sören Bock, Simon J. Higgins, Zahra Murtada Abd Dawood, Juan Hurtado-Gallego

Publikováno v: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Repositorio Institucional del Instituto Madrileño de Estudios Avanzados en Nanociencia
instname

The most probable single-molecule conductance of each member of a series of 12 conjugated molecular wires, 6 of which contain either a ruthenium or platinum center centrally placed within the backbone, has been determined. The measurement of a small,

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::23ee46c0631e28ade4db4b57c5954895
https://doi.org/10.1021/jacs.0c11605

Towards the design of effective multipodal contacts for use in the construction of Langmuir–Blodgett films and molecular junctions

Autor: Enrique Escorihuela, Sören Bock, Paul J. Low, Santiago Martín, Richard J. Nichols, David C. Milan, Pilar Cea, Henrry M. Osorio, Saman Naghibi

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
instname
JOURNAL OF MATERIALS CHEMISTRY C

As part of on-going efforts to optimize the electrical performance and stability of molecular electronic components, anchor groups that bind molecules to electrode surfaces via multiple points of connection (multipodal contacts) have begun to attract

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::65f16bc1bca9a7faefcfa83048439669
http://hdl.handle.net/10261/219180

Clusters as ligands: Synthesis, structure and coordination chemistry of ruthenium clusters derived from 4- and 5-ethynyl-2,2′-bipyridine

Autor: Paul J. Low, Campbell F. R. Mackenzie, George A. Koutsantonis, Lindsay T. Byrne, Brian W. Skelton, Sören Bock

Publikováno v: Journal of Organometallic Chemistry. 812:190-196

The reaction of [Ru3(CO)10(μ-dppm)] (1) with 4-ethynyl-2,2′-bipyridine (2) or 5-ethynyl-2,2′-bipyridine (3) affords the Ru3C2 clusters [Ru3(μ-H)(μ3-C2bpy)(CO)7(dppm)] (bpy = 4-bpy, 4 (22%); bpy = 5-bpy, 5 (55%)). Complexes 4 and 5 have been fu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d717b3ffbd26e3105b4720708568ecbc
https://doi.org/10.1016/j.jorganchem.2015.09.021

Coordinating Tectons. Experimental and Computational Infrared Data as Tools To Identify Conformational Isomers and Explore Electronic Structures of 4-Ethynyl-2,2′-bipyridine Complexes

Autor: Carlo Nervi, Duncan A. Wild, Sören Bock, George A. Koutsantonis, Paul J. Low, Brian W. Skelton, Chia Yang Lim, Campbell F. R. Mackenzie

4-Ethynyl-2,2′-bipyridyl-substituted ruthenium alkynyl complexes have been prepared and used to access a range of binuclear homometallic ruthenium and heterometallic ruthenium–rhenium complexes. These have been characterized by a variety of spect

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ec421309bd0897bfbd8892d5510423d0
http://hdl.handle.net/2318/1637917

Experimental and computational studies of single-molecule conductance of Ru(II) and Pt(II) trans-Bis(acetylide) complexes

Autor: Simon J. Higgins, Marie-Christine Oerthel, Judith A. K. Howard, Oday A. Al-Owaedi, David C. Milan, Richard J. Nichols, Dmitry S. Yufit, Sören Bock, Paul J. Low, Martin R. Bryce, Colin J. Lambert

Publikováno v: Organometallics, 2016, Vol.35(17), pp.2944-2954 [Peer Reviewed Journal]
ORGANOMETALLICS

The single-molecule conductance of metal complexes of the general forms trans-Ru(C≡CArC≡CY)2(dppe)2 and trans-Pt(C≡CArC≡CY)2(PPh3)2 (Ar = 1,4-C6H2-2,5-(OC6H13)2; Y = 4-C5H4N, 4-C6H4SMe) have been determined using the STM I(s) technique. The c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8362fc91ee6e0f11608bb40f65863f95
http://dro.dur.ac.uk/19648/2/19648.pdf