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Towards the design of effective multipodal contacts for use in the construction of Langmuir–Blodgett films and molecular junctions

Autor: Enrique Escorihuela, Sören Bock, Paul J. Low, Santiago Martín, Richard J. Nichols, David C. Milan, Pilar Cea, Henrry M. Osorio, Saman Naghibi

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
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JOURNAL OF MATERIALS CHEMISTRY C

As part of on-going efforts to optimize the electrical performance and stability of molecular electronic components, anchor groups that bind molecules to electrode surfaces via multiple points of connection (multipodal contacts) have begun to attract

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::65f16bc1bca9a7faefcfa83048439669
http://hdl.handle.net/10261/219180

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New routes to organometallic molecular junctions via a simple thermal processing protocol

Autor: Pilar Cea, Sören Bock, Samantha G. Eaves, Paul J. Low, Brian W. Skelton, Francesc Pérez-Murano, Santiago Martín, Ruben Ezquerra

Publikováno v: Digital.CSIC. Repositorio Institucional del CSIC
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Methods for forming single- and multiple-molecule junctions are key to the development of molecular electronics and the further study of allied electronic and electrical properties of molecules arising from through-molecule charge transport. The orga

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dbb4955afe9b45e8b5b69a8cf7e8b524
http://hdl.handle.net/10261/202327

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Clusters as ligands: Synthesis, structure and coordination chemistry of ruthenium clusters derived from 4- and 5-ethynyl-2,2′-bipyridine

Autor: Paul J. Low, Campbell F. R. Mackenzie, George A. Koutsantonis, Lindsay T. Byrne, Brian W. Skelton, Sören Bock

Publikováno v: Journal of Organometallic Chemistry. 812:190-196

The reaction of [Ru3(CO)10(μ-dppm)] (1) with 4-ethynyl-2,2′-bipyridine (2) or 5-ethynyl-2,2′-bipyridine (3) affords the Ru3C2 clusters [Ru3(μ-H)(μ3-C2bpy)(CO)7(dppm)] (bpy = 4-bpy, 4 (22%); bpy = 5-bpy, 5 (55%)). Complexes 4 and 5 have been fu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d717b3ffbd26e3105b4720708568ecbc
https://doi.org/10.1016/j.jorganchem.2015.09.021

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Towards molecular electronic devices based on 'all-carbon' wires

Autor: Andrea, Moneo, Alejandro, González-Orive, Sören, Bock, Marta, Fenero, I Lucía, Herrer, David C, Milan, Matteo, Lorenzoni, Richard J, Nichols, Pilar, Cea, Francesc, Perez-Murano, Paul J, Low, Santiago, Martin

Publikováno v: Nanoscale. 10(29)

Nascent molecular electronic devices based on linear 'all-carbon' wires attached to gold electrodes through robust and reliable C-Au contacts are prepared via efficient in situ sequential cleavage of trimethylsilyl end groups from an oligoyne, Me

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::afedc1e573e2f5e8f73d8d8c25727daa
https://pubmed.ncbi.nlm.nih.gov/29999063

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Coordinating Tectons. Experimental and Computational Infrared Data as Tools To Identify Conformational Isomers and Explore Electronic Structures of 4-Ethynyl-2,2′-bipyridine Complexes

Autor: Carlo Nervi, Duncan A. Wild, Sören Bock, George A. Koutsantonis, Paul J. Low, Brian W. Skelton, Chia Yang Lim, Campbell F. R. Mackenzie

4-Ethynyl-2,2′-bipyridyl-substituted ruthenium alkynyl complexes have been prepared and used to access a range of binuclear homometallic ruthenium and heterometallic ruthenium–rhenium complexes. These have been characterized by a variety of spect

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ec421309bd0897bfbd8892d5510423d0
http://hdl.handle.net/2318/1637917

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Planar-chiral phosphino alkenylferrocenes – Synthesis, solid-state structure and electrochemistry

Autor: Sören Bock, Alexander Hildebrandt, Heinrich Lang, Dieter Schaarschmidt

Publikováno v: Journal of Organometallic Chemistry. 751:742-753

The synthesis and characterization of phosphino alkenylferrocenes of type [Fe( η 5 -C 5 H 3 –2-PR′ 2 –( E )-CH = CHR)( η 5 -C 5 H 5 )] (R = C 6 H 5 , 4-Cl–C 6 H 4 , 4-OMe–C 6 H 4 , 4-Me–C 6 H 4 , 4-CN–C 6 H 4 , 4-Ac–C 6 H 4 , Fc; R�

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8d2ff5f0544e73e958f9300cc490be98
https://doi.org/10.1016/j.jorganchem.2013.07.080

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Experimental and computational studies of single-molecule conductance of Ru(II) and Pt(II) trans-Bis(acetylide) complexes

Autor: Simon J. Higgins, Marie-Christine Oerthel, Judith A. K. Howard, Oday A. Al-Owaedi, David C. Milan, Richard J. Nichols, Dmitry S. Yufit, Sören Bock, Paul J. Low, Martin R. Bryce, Colin J. Lambert

Publikováno v: Organometallics, 2016, Vol.35(17), pp.2944-2954 [Peer Reviewed Journal]
ORGANOMETALLICS

The single-molecule conductance of metal complexes of the general forms trans-Ru(C≡CArC≡CY)2(dppe)2 and trans-Pt(C≡CArC≡CY)2(PPh3)2 (Ar = 1,4-C6H2-2,5-(OC6H13)2; Y = 4-C5H4N, 4-C6H4SMe) have been determined using the STM I(s) technique. The c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8362fc91ee6e0f11608bb40f65863f95
http://dro.dur.ac.uk/19648/2/19648.pdf

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A Safe and Simple Synthesis of 1,4-Bis(trimethylsilyl)buta-1,3-diyne

Autor: Paul J. Low, Sören Bock

Publikováno v: Australian Journal of Chemistry. 71:307

The buta-1,3-diyne synthon 1,4-bis(trimethylsilyl)buta-1,3-diyne (1) is an important building block for the introduction of butadiyne motifs into organic and organometallic structures. Although 1 is commonly prepared from the Hay homo-coupling of tri

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::addaf21b86f1a6963b4665b87c207a36
https://doi.org/10.1071/ch17402

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