Capturing the Monomeric (L)CuH in NHC‐Capped Cyclodextrin: Cavity‐Controlled Chemoselective Hydrosilylation of α,β‐Unsaturated Ketones

Autor: Etienne Derat, Matthieu Sollogoub, Sylvain Roland, Olivier Riant, Guangcan Xu, Jorge Meijide Suárez, Sébastien Leloux, Tom Leyssens, Olivia Bistri-Aslanoff, Pinglu Zhang, Yongmin Zhang, Mickaël Ménand

Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2020, 59 (19), pp.7591-7597. ⟨10.1002/anie.202001733⟩
Angewandte Chemie International Edition, Vol. 59, no.19, p. 7591-7597 (2020)

International audience; The encapsulation of copper inside a cyclodextrin capped with an N ‐heterocyclic carbene (ICyD) allowed both to catch the elusive monomeric (L)CuH and a cavity‐controlled chemoselective copper‐catalyzed hydrosilylation o

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https://hal.sorbonne-universite.fr/hal-02748575