Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Sébastien Alazet"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 9, Iss 1, Pp 2354-2357 (2013)
The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts e
Externí odkaz:
https://doaj.org/article/200841140e5f4d37b0732ed69a94515b
Publikováno v:
Angewandte Chemie International Edition. 58:10300-10304
The efficient preparation of nitrile-containing building blocks is of interest due to their utility as synthetic intermediates and their prevalence in pharmaceuticals. As a result, significant efforts have been made to develop methods to access these
Autor:
Raphael Simonet-Davin, Thierry Meyer, Jerome Waser, Stefano Nicolai, Annik Nanchen, Johannes Preindl, Sébastien Alazet
Publikováno v:
The Journal of Organic Chemistry. 83:12334-12356
Azides are building blocks of increasing importance in synthetic chemistry, chemical biology, and materials science. Azidobenziodoxolone (ABX, Zhdankin reagent) is a valuable azide source, but its safety profile has not been thoroughly established. H
Publikováno v:
Chemistry – A European Journal. 23:9501-9504
A versatile synthesis of azidolactones through azidation and cyclization of carboxylic acids onto alkenes has been developed. Based on either photoredox or palladium catalysis, (1,1) and (1,2) azido lactones can be selectively synthesized. The choice
Autor:
Sébastien Alazet, Célestine Nkounkou Loumpangou, Thierry Billard, Hélène Carreyre, Jean-Maurille Ouamba, Sébastien Thibaudeau, Agnès Martin-Mingot, Gino Greco, Longin Justin Clair Bonazaba Milandou, Fodil Bouazza
Publikováno v:
Angewandte Chemie International Edition. 56:169-172
Upon activation under superacid conditions, functionalized tailor-made N-SCF3 sulfenamides served as reagents for the trifluoromethylthiolation of aromatic amines. This method has a broad substrate scope and can be used for the late-stage functionali
Publikováno v:
Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2015, 21 (42), pp.14694-14698. ⟨10.1002/chem.201502338⟩
Chemistry-A European Journal, Wiley-VCH Verlag, 2015, 21 (42), pp.14694-14698. ⟨10.1002/chem.201502338⟩
International audience; The most reactive 2nd generation of trifluoromethanesulfenamides undergoes a copper-catalyzed cross-coupling reaction with boronic acids to afford CF3S-molecules. Contrary to the previous methods in the literature, no base add
Publikováno v:
European Journal of Organic Chemistry. 2015:4607-4610
The α-trifluoromethylthiolation of carbonyl compounds in soft acidic conditions has been developed. With this method only mono-trifluoromethylthiolation was selectively observed. Base-sensitive ketones can then be trifluoromethylthiolated. More sens
Autor:
Hélène Carreyre, Longin Justin Clair Bonazaba Milandou, Sébastien Alazet, Fodil Bouazza, Célestine Nkounkou Loumpangou, Jean-Maurille Ouamba, Gino Greco, Thierry Billard, Agnès Martin-Mingot, Sébastien Thibaudeau
Publikováno v:
Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2017, 56 (1), pp.417-417. ⟨10.1002/anie.201611312⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2017, 56 (1), pp.417-417. ⟨10.1002/anie.201611312⟩
International audience
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dc578e4f7d3be3236b4fb23657af4f7b
https://hal.archives-ouvertes.fr/hal-01610196
https://hal.archives-ouvertes.fr/hal-01610196
Publikováno v:
European Journal of Organic Chemistry. 2014:2415-2428
Because of its high lipophilicity, the CF3S group has always interested chemists. However, strategies to introduce it into organic molecules have been, for the most part, reserved to specialized “fluorine chemists”. Recent published work has demy
Publikováno v:
Angewandte Chemie International Edition
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52 (41), pp.10814-10817. ⟨10.1002/anie.201305179⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2013, 52 (41), pp.10814-10817. ⟨10.1002/anie.201305179⟩
[*] S. Alazet, Dr. T. BillardInstitute of Chemistry and Biochemistry (ICBMS—UMR CNRS5246), Universit de Lyon, Universit Lyon 1, CNRS43 Bd du 11 novembre 1918, 69622 Lyon (France)E-mail: Thierry.billard@univ-lyon1.frS. Alazet, Prof. L. Zimmer, Dr. T