Výsledky vyhledávání - "Ryota Hirasawa"

Cyclic oligomer of oxide clusters through a siloxane bond. Synthesis and structure of reaction products of α2-mono-lacunary Dawson polyoxometalate with tetrachlorosilane and tetraethoxysilane

Autor: Ryota Hirasawa, Shoko Yoshida, Takayuki Kurashina, Yuhki Kasahara, Kenji Yoza, Takeshi Hasegawa, Shotaro Aoki, Kenji Nomiya

Publikováno v: Dalton Transactions. :5542

The title compound with the formula (Me2NH2)13H5[{alpha2-P2W17O61(Si2O)}3(micro-O)3].39H2O Me2NH(2)-1 was obtained in 12.8% (0.258 g scale) yield by a 1:2 molar ratio reaction of alpha2-mono-lacunary Dawson polyoxometalate (POM) [alpha2-P2W17O61]10-

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3cca25b65d34b33271e6a8f51744f712
https://doi.org/10.1039/b902904d

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Akademický článek

Cyclic oligomer of oxide clusters through a siloxane bond. Synthesis and structure of reaction products of α2-mono-lacunary Dawson polyoxometalate with tetrachlorosilane and tetraethoxysilaneElectronic supplementary information (ESI) available: Crystal data for Me2NH2−2; bond lengths () and angles (°) for 1(Table S1); bond valence sum (BVS) calculations for 1(Table S2). CCDC reference numbers 718728 for Me2NH2--1and 718729 for Me2NH2-2. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b902904d

Autor: Takayuki Kurashina, Shotaro Aoki, Ryota Hirasawa, Takeshi Hasegawa, Yuhki Kasahara, Shoko Yoshida, Kenji Yoza, Kenji Nomiya

Publikováno v: Dalton Transactions: An International Journal of Inorganic Chemistry; Jul2009, Vol. 2009 Issue 28, p5542-5550, 9p

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