Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Ryan M. Mackiewicz"'
Publikováno v:
Journal of the American Chemical Society. 127:14026-14038
The mechanism of the copolymerization of cyclohexene oxide and carbon dioxide to afford poly(cyclohexylene)carbonate catalyzed by (salen)CrN3 (H2salen = N,N,'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylene-diimine) in the presence of a broad range o
Publikováno v:
Organometallics. 24:144-148
The rate of the copolymerization reaction of cyclohexene oxide and carbon dioxide in the presence of (salen)CrIIIN3 and various cocatalysts has been determined as a function of CO2 pressure. Carbon dioxide insertion into the (salen)Cr-alkoxide interm
Publikováno v:
Catalysis Today. 98:485-492
Studies of the copolymerization of CO 2 and epoxides have been the staple of our group's research program for the better part of a decade now. During that time, the incorporation of attenuated total reflectance Fourier transform infrared (ATR/FTIR) s
Publikováno v:
ChemInform. 36
The design of efficient metal catalysts for the selective coupling of epoxides and carbon dioxide to afford completely alternating copolymers has made significant gains over the past decade. Hence, it is becoming increasingly clear that this “green
Publikováno v:
Accounts of chemical research. 37(11)
The design of efficient metal catalysts for the selective coupling of epoxides and carbon dioxide to afford completely alternating copolymers has made significant gains over the past decade. Hence, it is becoming increasingly clear that this “green
Autor:
Damon R. Billodeaux, Ryan M. Mackiewicz, Donald J. Darensbourg, Joseph H. Reibenspies, Cindy C Fang, Jody L Rodgers
Publikováno v:
Inorganic chemistry. 43(19)
A detailed mechanistic study into the copolymerization of CO2 and cyclohexene oxide utilizing CrIII(salen)X complexes and N-methylimidazole, where H2salen = N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylenediimine and other salen derivatives and X
Publikováno v:
Inorganic chemistry. 43(6)
The copolymerization of CO(2) and cyclohexene or propylene oxide has been examined employing (salen)Cr(III)Nu complexes (Nu = Cl or N(3)) as catalysts. The addition of various cocatalysts, including phosphines and PPN+ or Bu4N+ Cl- salts serves to gr