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pro vyhledávání: '"Ryan M. Kirk"'
Autor:
Callum M. Inglis, Richard A. Manzano, Ryan M. Kirk, Manab Sharma, Madeleine D. Stewart, Lachlan J. Watson, Anthony F. Hill
Publikováno v:
Molecules, Vol 28, Iss 23, p 7761 (2023)
A convenient synthesis of [HB(HImMe)3](PF6)2 (ImMe = N-methylimidazolyl) is decribed. This salt serves in situ as a precursor to the tris(imidazolylidenyl)borate Li[HB(ImMe)3] pro-ligand upon deprotonation with nBuLi. Reaction with [W(≡CC6H4Me-4)(C
Externí odkaz:
https://doaj.org/article/81ea30917c214755bbcf0c1bfc56d0fb
Publikováno v:
Chemical Communications. 57:8770-8773
Gold(I)-catalysed tandem transmetallation (Sn→Au→As) of the stannylcarbyne [W(≡CSnnBu3)(CO)2(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM≡CAsR2, includ
Autor:
Ryan M. Kirk, Anthony F. Hill
Publikováno v:
Chemical science. 13(23)
Cobalt carbonyl reacts with arsoles to provide the first late transition metal η5-arsolyls. These serve as ditopic donors to extraneous metal centres (M = PtII, AuI, HgII) through both conventional AsM and polar-covalent (dative) CoM interactions.
Autor:
Namsoon Eom, Ryan M. Kirk, Gunther G. Andersson, Gregory F. Metha, Vladimir B. Golovko, Gowri Krishnan
Publikováno v:
The Journal of Physical Chemistry C. 123:6642-6649
Atomically precise chemically synthesized gold clusters protected by diphenylphosphine ligands [(Au13(dppe)5Cl2)Cl3] (dppe = 1,2-bis(diphenylphosphino)ethane) were deposited onto a defect-rich, ato...