Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Ryan M Tipker"'
Protonation of P-Stereogenic Phosphiranes: Phospholane Formation via Ring Opening and C–H Activation
Autor:
Ryan M. Tipker, Jake A. Muldoon, Jacob Jo, Christopher S. Connors, Balazs R. Varga, Russell P. Hughes, David S. Glueck
Publikováno v:
ACS Omega. 8:12565-12572
Publikováno v:
Organometallics. 41:1721-1730
Autor:
David S. Glueck, Daniel H Pham, Balázs R. Varga, Gary J Balaich, Arnold L. Rheingold, Russell P. Hughes, Ryan M Tipker, Jake A. Muldoon
Publikováno v:
Angewandte Chemie International Edition. 61
Tetrahedral main-group compounds are normally configurationally stable, but P-epimerization of the chiral phosphiranium cations syn- or anti-[Mes*P(Me)CH2 CHPh][OTf] (Mes*=2,4,6-(t-Bu)3 C6 H2 ) occurred under mild conditions at 60 °C in CD2 Cl2 , re