Accessing Improbable Foldamer Shapes with Strained Macrocycles

Autor: Masatoshi Kawahata, Aya Tanatani, Vojislava Pophristic, Yann Ferrand, Kosuke Katagiri, Ko Urushibara, Ryan D'Elia, Ivan Huc, Zhiwei Liu, Estelle Morvan

Publikováno v: Chemistry (Weinheim an Der Bergstrasse, Germany)
Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, In press, ⟨10.1002/chem.202101201⟩

The alkylation of some secondary amide functions with a dimethoxybenzyl (DMB) group in oligomers of 8‐amino‐2‐quinolinecarboxylic acid destabilizes the otherwise favored helical conformations, and allows for cyclization to take place. A cyclic

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4cf43ce2ddf132521153d63dd965367e
http://europepmc.org/articles/PMC8453500