Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Ryan A. Ivanovich"'
Autor:
Jean-François Vincent-Rocan, André M. Beauchemin, Geneviève F. O'Keefe, Owen C. Lutes, Ryan A. Ivanovich, Claire Blanger, Alexandria D. M. Jeanneret, William Gagné-Monfette
Publikováno v:
Chemistry – A European Journal. 27:14051-14056
In contrast to carbon-substituted isocyanates that are common building blocks, N-substituted isocyanates remain underdeveloped and reports on their N-acyl derivatives (i. e. amido-isocyanates) are exceedingly rare. Herein, amido-isocyanates were inve
Publikováno v:
Organic Letters. 22:6360-6364
Nitrenes are remarkable high-energy chemical species that enable direct C-N bond formation, typically via controlled reactions of metal-stabilized nitrenes. Here, in contrast, the combined use of photocatalysis with careful engineering of the precurs
Autor:
Michael Raymond, Nicolas Das Neves, Jasper A. M. Quartus, Francis Loiseau, André M. Beauchemin, Ryan A. Ivanovich
Publikováno v:
The Journal of Organic Chemistry. 84:9792-9800
Aminimides are key intermediates in the thermal cycloadditions of suitable alkenyl-hydrazine derivatives. Substrate modifications (β-N,N-dialkyl) allowed the isolation of these reactive intermediates, and the analysis of their stereochemistry provid
Publikováno v:
Organic Letters. 24:6884-6884
Autor:
Rosalie Dalhoff, Sorin-Claudiu Roşca, Ryan A. Ivanovich, Laurel L. Schafer, Pargol Daneshmand, Dilan E. Polat, André M. Beauchemin, Kejun Yin, Rebecca C. DiPucchio
Publikováno v:
Journal of the American Chemical Society. 142(37)
The efficient and catalytic amination of unactivated alkenes with simple secondary alkyl amines is preferentially achieved. A sterically accessible, N,O-chelated cyclic ureate tantalum catalyst was...
Publikováno v:
Advanced Synthesis & Catalysis. 359:4289-4293
Oxygen-substituted isocyanates (O-isocyanates) are rare isocyanates with a reported propensity to trimerize, a side-reaction that severely limited their use in synthesis. Herein, the development of blocked (masked) O-isocyanate precursors that form t
Autor:
Jean-François Vincent-Rocan, Christian Clavette, Andre M. Beauchemin, Ryan A. Ivanovich, Serge I. Gorelsky, Jean‐Gregoire Roveda
Publikováno v:
Chemistry - A European Journal. 22:7906-7916
The ubiquity of nitrogen heterocycles in biologically active molecules challenges synthetic chemists to develop a variety of tools for their construction. While developing metal-free hydroamination reactions of hydrazine derivatives, it was discovere
Autor:
Julien Bejjani, Ryan A. Ivanovich, Kyle Leckett, Jean-François Vincent-Rocan, Andre M. Beauchemin, Christian Clavette
Publikováno v:
Chemical Science. 7:315-328
In contrast to normal C-substituted isocyanates, nitrogen-substituted isocyanates (N-isocyanates) are rare. Their high reactivity and amphoteric/ambident nature has prevented the scientific community from exploiting their synthetic potential. Recentl
Publikováno v:
Organic Letters. 17:4898-4901
A one-pot sequence for the synthesis of aza-diketopiperazines is reported, involving carbazate acylation with chloroacetyl chloride, SN2 with a primary amine, N-isocyanate formation, and cyclization. Nitrogen-substituted isocyanates (N-isocyanates) a
Autor:
Christian Clavette, Andre M. Beauchemin, Ryan A. Ivanovich, Jean-François Vincent-Rocan, Serge I. Gorelsky, Jean‐Gregoire Roveda
Publikováno v:
ChemInform. 47
The ubiquity of nitrogen heterocycles in biologically active molecules challenges synthetic chemists to develop a variety of tools for their construction. While developing metal-free hydroamination reactions of hydrazine derivatives, it was discovere