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pro vyhledávání: '"Ruth Flügel"'
Publikováno v:
Chemische Berichte. 130:493-506
The coordinatively unsaturated starting materials trans-[OsCl(NO)PiPr3)2] (2) and trans- [(sCl(NO)(PiPr2Ph)2] (3), for which a new one-pot synthesis is reported, react with isocyanides, SO2 and O2 to give the corresponding 1:1 adducts [OsCl(NO)(L)(P)
Publikováno v:
Chemische Berichte. 129:1007-1013
The reduction of [RuCl3(NO)(PPh3)2] (1) with Zn/Cu generates [RuCl(NO)(PPh3)2] that by ligand exchange with PR3 (R3 iPr3, iPr2Ph) affords the stable 16-electron ruthenium (0) complexes trans-[RuCl(NO)(PR3)2] (2, 3). The X-ray structural analysis of 2
Publikováno v:
Chemische Berichte. 129:405-410
Addition of CS2 and Other Heteroallenes to the 16-Electron Osmium(0) Complexes trans-[OsCl(NO)(PiPr2R)2] The coordinatively unsaturated 16-electron compounds trans-[OsCl(NO)(PiPr2R)2] (1: R = iPr; 2: R = Ph) react with CS2 and COS to form the 1:1 add