Zobrazeno 1 - 10
of 21
pro vyhledávání: '"Ruth Castro-Rodrigo"'
Autor:
Montserrat Oliván, Miguel A. Esteruelas, Virginia Lezáun, Ana M. López, Daniel Gómez-Bautista, Ruth Castro-Rodrigo, Enrique Oñate
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The study of the reactions of IrH5(PiPr3)2 (1) with 2,6-diphenylpyridine and 2-phenoxy-6-phenylpyridine and the photophysical characterization of some of the resulting compounds, as well as their osmium counterparts, reveal that the bite angle of dia
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::284f1807cfc5938d3054521471a860c6
https://doi.org/10.1021/acs.organomet.9b00466
https://doi.org/10.1021/acs.organomet.9b00466
Autor:
Lloyd Munjanja, Sumit Chakraborty, William D. Jones, Ruth Castro-Rodrigo, William W. Brennessel
Publikováno v:
Organometallics. 35:3124-3131
A new series of molybdenum and tungsten tricarbonyl pincer complexes, bearing pyridine-based PONOP-type pincer ligands, have been synthesized and fully characterized. Addition of HBF4·Et2O to these tricarbonyl complexes generated seven-coordinate mo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c389faee9f5cdbeb570d28e9b55ddddb
https://doi.org/10.1021/acs.organomet.6b00461
https://doi.org/10.1021/acs.organomet.6b00461
Autor:
Ruth Castro-Rodrigo, Enrique Oñate, Ana M. López, Miguel A. Esteruelas, Cristina García-Yebra, María Batuecas
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Zaguán. Repositorio Digital de la Universidad de Zaragoza
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Zaguán. Repositorio Digital de la Universidad de Zaragoza
In memory of José Barluenga (1940–2016).
The aromatic osmacyclopropenefuran bicycles [OsTp{κ3-C1,C2,O-(C1H2C2CHC(OEt)O)}(PiPr3)]BF4 (Tp=hydridotris(1-pyrazolyl)borate) and [OsH{κ3-C1,C2,O-(C1H2C2CHC(OEt)O)}(CO)(PiPr3)2]BF4, with the metal f
The aromatic osmacyclopropenefuran bicycles [OsTp{κ3-C1,C2,O-(C1H2C2CHC(OEt)O)}(PiPr3)]BF4 (Tp=hydridotris(1-pyrazolyl)borate) and [OsH{κ3-C1,C2,O-(C1H2C2CHC(OEt)O)}(CO)(PiPr3)2]BF4, with the metal f
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9f5ab55cf9342c4592dfac360824a6e0
https://pubmed.ncbi.nlm.nih.gov/27701801
https://pubmed.ncbi.nlm.nih.gov/27701801
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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One of the acetone molecules of the solvento complex [OsTp(κ 1-OCMe 2) 2(P iPr 3)]BF 4 (1; Tp = hydridotris(1-pyrazolyl)borate) is displaced by cyclohexylallene to give [OsTp(η 2-CH 2=C=CHCy) (κ 1-OCMe 2)(P iPr 3)]BF 4 (2). Treatment of 2 with a s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f3d4a58447ece5da68540ed6807f53ac
https://doi.org/10.1021/om201272q
https://doi.org/10.1021/om201272q
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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The reactions of the bis(solvento) complexes [OsCp(MeCN)2(PiPr3)]PF6 (1; Cp = cyclopentadienyl) and [OsTp(κ1-OCMe2)2(PiPr3)]BF4 (1a; Tp = hydridotris(pyrazolyl)borate) with allenes have been investigated. Complex 1 reacts with 1-methyl-1-(trimethyls
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6d2e81856f52fe4ed17f577309c454fd
https://doi.org/10.1021/om100568r
https://doi.org/10.1021/om100568r
Autor:
Ruth Castro-Rodrigo, Miguel A. Esteruelas, Ana M. López, Silvia Mozo, Enrique Oñate, Sara Fuertes
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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Complex [OsTp(K1-OCMe2)2(P iPr3)]BF4 (1; Tp = hydridotris(pyrazolyl) borate) reacts with 2-vinylpyridine to give the olefin derivative [OsTp(n 2-CH2=CH-C5H4N)(PiPr 3)]BF4 (2). In methanol at 60 °C, complex 2 is in equilibrium with its alkylidene iso
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5d467d8b274e3161f5eded3ce345ef47
https://doi.org/10.1021/om900635p
https://doi.org/10.1021/om900635p
Autor:
Enrique Oñate, Fernando López, José L. Mascareñas, Miguel A. Esteruelas, Silvia Mozo, Lucía Saya, Ana M. López, Ruth Castro-Rodrigo
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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instname
5 páginas, 1 figura, 1 esquema, 1 tabla.
The reactions of (2-pyridyl)methylenecyclobutane with the metal fragments [OsTp(PiPr3)]þ and [OsCp(PiPr3)]þ (Tp = hydridotris(pyrazolyl)borate, Cp = cyclopentadienyl) are shown. Complex [OsTp(κ1-OCMe2
The reactions of (2-pyridyl)methylenecyclobutane with the metal fragments [OsTp(PiPr3)]þ and [OsCp(PiPr3)]þ (Tp = hydridotris(pyrazolyl)borate, Cp = cyclopentadienyl) are shown. Complex [OsTp(κ1-OCMe2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3b7c8082a070e6cb9f89428041697209
http://hdl.handle.net/10261/37314
http://hdl.handle.net/10261/37314
Autor:
José L. Mascareñas, Montserrat Oliván, Lara Villarino, Fernando López, Lucía Saya, Ruth Castro-Rodrigo, Ana M. López, Miguel A. Esteruelas, Enrique Oñate
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
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2 páginas, 1 figura, 2 esquemas.
The complex [OsTp(κ1-OCMe)2(PiPr3)]BF4 [Tp = hydridotris(pyrazolyl)borate] promotes the cleavage of both C(sp3)−C(sp2) bonds of benzylidenecyclopropane and 3-phenylpropylidenecyclopropane to yield the complex
The complex [OsTp(κ1-OCMe)2(PiPr3)]BF4 [Tp = hydridotris(pyrazolyl)borate] promotes the cleavage of both C(sp3)−C(sp2) bonds of benzylidenecyclopropane and 3-phenylpropylidenecyclopropane to yield the complex
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::be877d229376cc01369a6e810293c652
http://hdl.handle.net/10261/20938
http://hdl.handle.net/10261/20938
Autor:
Enrique Oñate, Sara Fuertes, Miguel A. Esteruelas, José L. Mascareñas, Ana M. López, Ruth Castro-Rodrigo, Fernando López, Lucía Saya, Silvia Mozo, Lara Villarino
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
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Alkylidenecyclopropanes containing a chelation assistant at the terminal carbon atom of the olefinic moiety undergo an Os- or Ru-promoted ring expansion reaction to afford metal cyclobutylidene derivatives. The process occurs through a novel mechanis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7eeec09fb1a2b4696f85f946167b290e
https://pubmed.ncbi.nlm.nih.gov/19817442
https://pubmed.ncbi.nlm.nih.gov/19817442
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
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The dihydrogen complex [OsTp(η2-H2) (κ1-OCMe2)(PiPr3)]BF 4 (1; Tp = hydridotris(pyrazolyl)borate) reacts with tert-butylacetylene to give the hydride-carbyne derivative [OsHTp(≡ CCH2 tBu)(PiPr3)]BF4 (2). Similarly, the treatment of 1 with (trimet
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::68301abeb5bf5ef8fe928a5bc10b29c4
http://hdl.handle.net/10261/64936
http://hdl.handle.net/10261/64936