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The hydrogen fluoride (HF) molecule is seen in absorption in the interstellar medium (ISM) along many lines of sight. It is surprisingly observed in emission toward the Orion Bar, which is an interface between the ionized region around the Orion Trap
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https://explore.openaire.eu/search/publication?articleId=doi_dedup___::43d2c7ffa9825638282ef1f438666580