Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Russell F. Lang"'
Publikováno v:
Inorganica Chimica Acta. 348:157-164
Reactions of W(CO)3(phen)(EtCN) with butane thiols, thiophenol, 1,2-benzenedithiol, and 3,4-toluenedithiol have been investigated. Reaction of butanethiol results in simple ligand exchange to form the thiol complex W(CO)3(phen)(n or tBuSH). Reaction
Publikováno v:
Journal of Surfactants and Detergents. 2:503-513
Specific lengths of the fatty and polyoxyethylene chains of ethoxylated fatty amines are critical to their performance in specific applications, and thus the ability to characterize these surfactants accurately is crucial. Normal-phase high-performan
Publikováno v:
Inorganica Chimica Acta. 270:488-498
The rate of oxidative addition of methyl disulfide in the complex W(CO)3(1,10-phenanthroline) (MeSSMe) in methylene chloride has been studied. The dominant reaction pathway is second order in metal complex and inhibited by excess methyl disulfide. Fo
Publikováno v:
Inorganic Chemistry. 36:614-621
The enthalpies of reaction of the ·Cr(CO)3C5Me5 and disulfides (RSSR) forming RS−Cr(CO)3C5Me5 have been measured by solution calorimetry, ΔH = −13.3 + 1.5 kcal/mol (R = Ph) and −11.2 + 1.2 kcal/mol (R = Me). These data lead to Cr−SR bond st
Autor:
Steven P. Nolan, Alberto A. Gonzalez, Russell F. Lang, Shakti L. Mukerjee, Carl D. Hoff, Telvin D. Ju
Publikováno v:
Inorganica Chimica Acta. 240:175-182
The enthalpies of reaction of HMo(CO) 3 C 5 R 5 (R = H, CH 3 ) with diphenyldisulfide producing PhSMo(CO) 3 C 5 R 5 and PhSH have been measured in toluene and THF solution (R = H, ΔH = −8.5 ± 0.5 kcal mol −1 (tol), −10.8 ± 0.7 kcal mol −1
Autor:
Songshen Zhang, Telvin D. Ju, Jian Kun Shen, Gabor Kiss, Fred Basolo, Russell F. Lang, Carl D. Hoff
Publikováno v:
Organometallics. 13:3692-3702
Publikováno v:
Inorganic Chemistry. 33:3899-3907
The complex W(CO){sub 3}(phen)(EtCN) undergoes oxidative addition with disulfides forming the formally 16-electron complexes W(CO){sub 2}(phen)(SR){sub 2}(R=Ph, {sup t}Bu, Me, benzyl). The reactions proceed through intermediates identified spectrosco
Publikováno v:
Inorganic Chemistry. 31:4885-4889
Enthalpies of ligand substitution based on reaction of (cycloheptatriene)Cr(CO)3, (naphthalene)Cr(CO)3, (cycloheptatriene)W(CO)3, (EtCN)3W(CO)3, and (arene)W(CO)3 complexes with a series of ligands have been measured by solution calorimetry. These da
Autor:
Russell F. Lang, Cheryl J. Brown
Publikováno v:
Analytical Chemistry. 63:186-189
Dimethyl sulfoxide (DMSO) and dimethyl sulfone (DMSO{sub 2}) are believed to be intermediates in the marine atmospheric oxidation pathway of dimethyl sulfide (DMS) to SO{sub 2} and sulfate. This report presents for the first time, an analytical metho
Autor:
Alexander A. P. Pszenny, C. J. Brown, James N. Galloway, J. T. Merrill, George R. Harvey, William C. Keene, Russell F. Lang
Publikováno v:
Global Biogeochemical Cycles. 4:367-379
Chemical data derived from air and precipitation samples collected during the Global Change Expedition/Coordinated Air-Sea Experiment/ Western Atlantic Ocean Experiment (GCE/CASE/WATOX) over the North Atlantic Ocean (NAO) are interpreted using simple