Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Rupert Edward Von Haken Spence"'
Autor:
Silke Courtenay, Todd Graham, Douglas W. Stephan, Pingrong Wei, Emily Hollink, Daryll G. Harrison, Wei Xu, Chad Beddie, James E. Kickham, Linda Koch, Aaron J. Hoskin, Jeffrey C. Stewart, Rupert Edward Von Haken Spence, Frédéric Guérin, Xiaoliang Gao
Publikováno v:
Organometallics. 22:1937-1947
A strategy for polymerization catalyst design has been developed based on the steric and electronic analogy of bulky phosphinimides to cyclopentadienyl ligands. To this end, the family of complexes of the form (Cp†)TiCl2(NPR3) has been prepared and
Autor:
John William Swabey, Douglas W. Stephan, Matthew G Kowalchuk, Steve J. Brown, Rupert Edward Von Haken Spence, Xiaoliang Gao
Publikováno v:
Canadian Journal of Chemistry. 80:1618-1624
A new class of titanium complexes containing a tropidinyl (trop) ligand and a phosphinimido (R3P=N-) or a ketimide ligand (R2C=N-) were synthesized and characterized. The combination of the cyclopentadienyl equivalent tropidinyl and phosphinimido lig
Publikováno v:
The Journal of Organic Chemistry. 59:2997-3002
Reduction of 5-(methylthio)-1,4,2-dithiazolium (3, R=H, Me, Ph) salts with zinc powder yields the corresponding diazahexathioorthooxalate derivatives (RCNS 2 ) (MeS)CC(SMe) (S 2 NCR) (4, R=H, Me, Ph). Thermolysis of these materials in the presence of
Autor:
Pierre Losier, Neil Burford, Bruce W. Royan, Robin D. Rogers, John F. Richardson, Simon Mason, T. Stanley Cameron, Rupert Edward Von Haken Spence, B. Borecka, Pradip K. Bakshi
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 76:17-20
The factors responsible for the isolation or identification of (carbenic) phosphenium and (alkenic) tricoordinate phosphonium salts are discussed. Structural features, reactivity and observations of intramolecular rearrangement are presented, which i
Autor:
Johann Weidlein, Yoshito Okada, Anders Hallberg, John F. Richardson, Rupert Edward Von Haken Spence, Stephen L. Buchwald, Rolf Svenson, Ahmad Nasiri, Michael Greune, Jörgen Alvhäll
Publikováno v:
Acta Chemica Scandinavica. 47:326-329
Autor:
Neil Burford, J. Marc Whalen, Rupert Edward Von Haken Spence, Robin D. Rogers, John F. Richardson
Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 64:137-144
A study of the interaction of imino-, oxo-, thio- and seleno- phosphorylic systems with Lewis acids has produced a number of interesting results, which represent a significant experimental contribution towards our understanding of the phosphorylic sy
Publikováno v:
J. Chem. Soc., Dalton Trans.. :1615-1619
Reactions between diaminoiminophosphinic chlorides and the chloride-abstracting agents AlCl3 and Ag(SO3CF3) have been comprehensively examined as potential routes to the three-co-ordinate iminophosphonium cation. However, bis(dialkylamino)(phenylimin
Autor:
John William Swabey, Linda Koch, Daryll G. Harrison, Peter Zoricak, Wei Xu, Rupert Edward Von Haken Spence, Douglas W. Stephan, Xiaoliang Gao, Frédéric Guérin, Qinyan Wang, Steve J. Brown
Publikováno v:
Organometallics. 18:2046-2048
The bis(tri-tert-butylphosphinimide) complexes (t-Bu3PN)2TiCl2 (1) and (t-Bu3PN)2TiMe2 (2) were prepared and characterized crystallographically. Stoichiometric reactions of 2 with PhNMe2H[B(C6F5)4] in the presence of PMe3 afforded [(t-Bu3PN)2TiMe(PMe
Autor:
Wei Xu, Jeffrey C. Stewart, Rupert Edward Von Haken Spence, Douglas W. Stephan, Frédéric Guérin, Daryll G. Harrison
Publikováno v:
Organometallics. 18:1116-1118
Complexes of the form (Cp†)TiCl2(NPR3) and the analogous dimethyl derivatives (Cp†)TiMe2(NPR3) have been prepared. These species in the presence of MAO, B(C6F5)3, or [Ph3C][B(C6F5)4] are active catalysts for ethylene polymerization.
Publikováno v:
J. Chem. Soc., Dalton Trans.. :2111-2117
A series of compounds with the general formula R3PE·AlCl3(R = Ph or NMe2, E = S or Se) has been examined by n.m.r. spectroscopy as a contribution toward the characterisation of the P–E bond and of the co-ordinate bond. Two derivatives, Ph3PS·AlCl