Zobrazeno 1 - 10
of 48
pro vyhledávání: '"Rui H. Huang"'
Autor:
Qingshan, Xie, Rui H, Huang, Andrew S, Ichimura, Richard C, Phillips, William P, Pratt, James L, Dye
Publikováno v:
Journal of the American Chemical Society. 122(29)
This is the sixth electride whose crystal structure has been determined and the fourth to show polymorphism. Crystals of the title electride prepared from mixed solvents have a structure similar to that of Li
Autor:
Mathew J. Vetticatt, Anil K. Gupta, Li Huang, Rui H. Huang, Xiaopeng Yin, Gang Hu, Wenjun Zhao, Joseph A. Izzo, Wynter E. G. Osminski, William D. Wulff
Publikováno v:
Journal of the American Chemical Society. 139(30)
VANOL and VAPOL ligands are known to react with three equivalents of B(OPh)3 to form a catalytic species that contains a boroxinate core with three boron atoms, and these have proven to be effective catalysts for a number of reactions. However, it wa
Publikováno v:
Chemistry - A European Journal. 18:5302-5313
The catalytic asymmetric aziridination of imines and diazo com- pounds (AZ reaction) mediated by boroxinate catalysts derived from the VANOL and VAPOL ligands was in- vestigated with chiral imines derived from five different chiral, disubstituted, me
Publikováno v:
Journal of the American Chemical Society. 127:12416-12422
An electride has been synthesized that is stable to auto-decomposition at room temperature. The key was the theoretically directed synthesis of a per-aza analogue of cryptand[2.2.2] in which each of the linking arms contains a piperazine ring. This c
Publikováno v:
Journal of the American Chemical Society. 125:2259-2263
The first barium sodide, with stoichiometry Ba(2+)(H(5)Azacryptand[2.2.2](-))Na(-).2MeNH(2), was synthesized by the reaction of Ba, Na, and H(6)Azacryptand[2.2.2] in NH(3)-MeNH(2) solution. It was characterized by X-ray crystallography, (23)Na MAS NM
Autor:
Richard C. Phillips, William P. Pratt, Rui H. Huang, James L. Dye, Qingshan Xie, Andrew S. Ichimura
Publikováno v:
Journal of the American Chemical Society. 122:6971-6978
This is the sixth electride whose crystal structure has been determined and the fourth to show polymorphism. Crystals of the title electride prepared from mixed solvents have a structure similar to that of Li+(cryptand[2.1.1])e-. Electrons occupy cav
Autor:
James L. Dye, François X. Sauvage, Julius Lema, Franck Demol, Lawrence P. Szajek, Amy Burns, Rui H. Huang, James E. Jackson, Marc G. DeBacker, Qingshan Xie, Andrew S. Ichimura
Publikováno v:
The Journal of Physical Chemistry A. 104:3038-3047
The macrobicyclic Schiff base cryptand, 1, with a m-phenyl group in each of the arms was reduced in tertrahydrofuran with the alkali metals Na through Cs to yield mono-, di-, and trianions. The crystal structure of a salt of 1-, formed by reduction o
Publikováno v:
The Journal of Physical Chemistry B. 104:1078-1087
Crystalline Cs+(18-crown-6)2e- was found to be a linear chain Heisenberg antiferromagnet (J/kB = −38.3 K). It undergoes a slow, irreversible transition above ∼230 K from a crystalline low temperature (LT) phase to a disordered Curie−Weiss param
Publikováno v:
Journal of the American Chemical Society. 131:15615-15617
Studies are described that were designed to determine the structure of the active catalyst in the asymmetric catalytic aziridination of imines with ethyl diazoacetate (AZ reaction). Evidence suggests that the active catalyst contains a boroxine ring
Publikováno v:
Angewandte Chemie International Edition. 38:1751-1755
Light at the end of the tunnel! Intercalates of pyridine and layered inorganic compounds have intrigued chemists for at least two decades, but their structure determination has always been difficult owing to a lack of suitable single crystals. The in