Zobrazeno 1 - 10
of 35
pro vyhledávání: '"Rostam J. Madon"'
Autor:
James A. Dumesic, Canan Sener, David H. K. Jackson, Insoo Ro, Yifei Liu, Thomas F. Kuech, Joseph P. Chada, Rostam J. Madon, George W. Huber, Madelyn R. Ball
Publikováno v:
ACS Catalysis. 6:7040-7050
Well-defined Cu catalysts containing different amounts of zirconia were synthesized by controlled surface reactions (CSRs) and atomic layer deposition methods and studied for the selective conversion of ethanol to ethyl acetate and for methanol synth
Autor:
Nitin Agarwal, Randy D. Cortright, Marco A. Sanchez-Castillo, Andy Bartsch, Rostam J. Madon, James A. Dumesic
Publikováno v:
Journal of Catalysis. 218:88-103
Reaction kinetics data were collected for the conversion of isobutane over H-mordenite and β -zeolite, under conditions where reaction was initiated primarily by addition of isobutylene to the feed and where stable catalyst performance was achieved.
Publikováno v:
Industrial & Engineering Chemistry Research. 42:426-433
Testing of fluid cracking catalysts in laboratory microactivity units is carried out in either fixed- or fluid-bed reactors. The latter are becoming increasingly popular because of the automation they provide. This paper focuses on understanding the
Autor:
Marco A. Sanchez-Castillo, James A. Dumesic, Randy D. Cortright, and Rostam J. Madon, Nitin Agarwal
Publikováno v:
Industrial & Engineering Chemistry Research. 41:4016-4027
Reaction kinetics analyses were conducted for isobutane and 2-methylhexane conversion over USY zeolite (both calcined and steam-treated) at 773 K, where reaction is initiated by activation of the reactant paraffin. These analyses indicate that increa
Publikováno v:
Journal of Catalysis. 207:237-246
A large amount of research in fluid catalytic cracking (FCC) has focused on understanding the destructive role of vanadium, since it is a major issue for catalyst performance during the cracking of residuum-containing feeds. Here, we establish a mech
Autor:
Nitin Agarwal, Marco A. Sanchez-Castillo, Christian Miller, Randy D. Cortright, James A. Dumesic, Rostam J. Madon
Publikováno v:
Journal of Catalysis. 205:67-85
Reaction kinetics studies were conducted for isobutane conversion over a USY zeolite catalyst at a total pressure of 1 atm and for temperatures of 523 and 573 K. The catalyst is inactive for isobutane conversion in the absence of feed olefins at thes
Autor:
Rostam J. Madon, Enrique Iglesia
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 163:189-204
Chemical reactions reflect the universal tendency of systems to approach equilibrium. The dynamics towards equilibrium, reflected in rates of chemical reactions, are therefore influenced only by thermodynamic properties, such as reaction affinity and
Publikováno v:
Journal of Catalysis. 186:134-146
Kinetic analysis of experimental data for 2-methylhexane cracking demonstrates that trends in activity and selectivity are well simulated by adjusting a single parameter that represents the acid strength of a Y-based FCC catalyst. This acid strength
Publikováno v:
Topics in Catalysis. 4:15-26
Catalytic cracking of hydrocarbons takes place via elementary reactions such as initiation processes to form carbenium ions, olefin adsorption/desorption steps, isomerization, β-scission, oligomerization, and hydride ion transfer steps. These elemen
Publikováno v:
Journal of Catalysis. 165:205-220
We have formulated a quantitative kinetic model for analyzing the catalytic cracking of 2-methylhexane over USY-zeolite-based catalysts. The model is based on carbocation chemistry which includes carbenium ion initiation, isomerization, olefin desorp