Photolysis of Tertiary Amines in the Presence of CO2: The Paths to Formic Acid, α-Amino Acids, and 1,2-Diamines

Autor: María Elena González Núñez, Rossella Mello, Rafael Acerete, Mateo Berton

Publikováno v: Berton, Mateo Otao Mello, Rossella C. C. Acerete, Rafael González Núñez, María Elena 2018 Photolysis of tertiary amines in the presence of CO2: the paths to formic acid, α-amino acids, and 1,2-diamines Journal of Organic Chemistry 83 1 96 103
RODERIC. Repositorio Institucional de la Universitat de Valéncia
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The photolysis of triethylamine (1a) in the presence of carbon dioxide leads to the hydrogenation of CO2, the α-C-C coupling of triethylamine (1a), and the CO2-insertion into the α-C-H σ-bond of amine 1a. This reaction is proposed to proceed throu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::55d147358675d0b123b5e0c720a2b983
https://doi.org/10.1021/acs.joc.7b02407

Photolysis of Tertiary Amines in the Presence of CO

Autor: Mateo, Berton, Rossella, Mello, Rafael, Acerete, María Elena, González Núñez

Publikováno v: The Journal of organic chemistry. 83(1)

The photolysis of triethylamine (1a) in the presence of carbon dioxide leads to the hydrogenation of CO

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e22d5ba07ac5a39c5a2344c49565f1cd
https://pubmed.ncbi.nlm.nih.gov/29239181

Catalytic Functionalization of Methane and Light Alkanes in Supercritical Carbon Dioxide

Autor: Andrea Olmos, M. Ángeles Fuentes, M. Elena González‐Núñez, Ana Caballero, Pedro J. Pérez, Bianca K. Muñoz, Gregorio Asensio, Michel Etienne, Kane Jacob, Rossella Mello

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2014, 20 (35), pp.11013-11018. ⟨10.1002/chem.201403217⟩

International audience; The development of catalytic methods for the effective functionalization of methane yet remains a challenge. The best system known to date is the so-called Catalytica Process based on the use of platinum catalysts to convert m

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0eae74c8e9f390c42ae58000d59523ac
https://doi.org/10.1002/chem.201403217

Supercritical Carbon Dioxide: A Promoter of Carbon-Halogen Bond Heterolysis

Autor: Andrea Olmos, Rossella Mello, Ana Caballero, Gregorio Asensio, Jaime Martínez-Ferrer, Pedro J. Pérez, María Elena González-Núñez, Thais Delgado-Abad

Publikováno v: Angewandte Chemie. 125:13540-13543

as the leaving groupdeparts from the carbon atom prior to the entrance of thenucleophile. Polar protic solvents with high dielectric con-stants promote polar bond heterolysis by providing effectiveH-bonding and electron-pair donation interactions to

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::90ede8716c77d450e563b4f074c27171
https://doi.org/10.1002/ange.201303819

Epoxidation of Olefins with a Silica-Supported Peracid

Autor: Ana Alcalde-Aragonés, Gregorio Asensio, María Elena González Núñez, Rossella Mello

Publikováno v: The Journal of Organic Chemistry. 77:6409-6413

Anhydrous [2-percarboxyethyl] functionalized silica (2a) is an advantageous oxidant for performing the epoxidation of olefins 1. Epoxides 3 do not undergo the ring-opening reactions catalyzed by the acidic silica surface, except for particularly acti

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4d89da98567d79dd54f6ccbf11c4cd2
https://doi.org/10.1021/jo300533b