Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Ross D. Bemowski"'
Publikováno v:
Organometallics. 34:4567-4573
A series of rare nitrido cyclopentadienyl complexes have been prepared of chromium(VI). An improved synthesis of NCr(I)(NPri2)2 is provided, which reacts with NaCp to give NCr(η1-Cp)(NPri2)2 (1) in 82% isolated yield. The η1-indenyl complex 2 can b
Autor:
Ross D. Bemowski, Louis Messerle, Dale C. Swenson, Adil Mohammad, Justine R. Olson, David A. Rotsch
Publikováno v:
Organometallics. 32:6232-6239
Ta(hpp)Cl4, Ta(hpp)2Cl3, and (η-C5Me4R)Ta(hpp)Cl3 (R = Me, Et; hpp = anion of 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine, hppH) are readily formed in good to excellent yields by addition of (hpp)SiMe3 to TaCl5, Ta(hpp)Cl4, or (η-C5Me4R)TaCl
Publikováno v:
Dalton Transactions. 43:12299
Amido rotation in the chromium(vi), d(0)-system NCr(NPr(i)2)2X is under investigation as a method for the parameterization of ligands for their donor properties toward high valent metals. In this study, two new series were prepared and studied based
Publikováno v:
Organometallics; Sep2015, Vol. 34 Issue 18, p4567-4573, 7p