Zobrazeno 1 - 10
of 245
pro vyhledávání: '"Ross A. Widenhoefer"'
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-10 (2023)
Abstract Allosteric control of reaction thermodynamics is well understood, but the mechanisms by which changes in local geometries of receptor sites lower activation reaction barriers in electronically uncoupled, remote reaction moieties remain relat
Externí odkaz:
https://doaj.org/article/ed4e1410ac60421583306f0efce95dd5
Publikováno v:
ACS Catalysis. 12:13941-13950
Publikováno v:
Organometallics. 41:2753-2763
Publikováno v:
Organometallics. 41:1106-1114
Publikováno v:
Organometallics. 40:1071-1076
The diastereomerically pure azaplatinacyclobutane complex , bearing a single deuterium atom at Cα, undergoes stereomutation about the Cα–Cβ bond of the azaplatinacyclobutane moiety at 30 °C with a ...
Autor:
Liqi Wang, Yichen Yu, Chenxu Wang, Ross A. Widenhoefer, Stephen L. Craig, Roman Boulatov, Cai-Li Sun
Publikováno v:
Chemical Science
CHEMICAL SCIENCE
CHEMICAL SCIENCE
Coupled mechanical forces are known to drive a range of covalent chemical reactions, but the effect of mechanical force applied to a spectator ligand on transition metal reactivity is relatively unexplored. Here we quantify the rate of C(sp2)–C(sp2
Autor:
Ross A. Widenhoefer, Nana Kim
Publikováno v:
Organometallics. 39:3160-3167
Treatment of the gold 3-methoxy-3-phenylpropyl complex (P)AuCH2CH2CH(OMe)Ph [P = P(t-Bu)2o-biphenyl] with AlCl3 at −78 °C led to the immediate (≤5 min) formation of a 4:1 mixture of phenylcycloprop...
Autor:
Caroline P. Stow, Ross A. Widenhoefer
Publikováno v:
Organometallics. 39:1249-1257
The trifluoromethanesulfonate α-oxo carbenoid complexes (IPr)AuCH(OTf)COR [R = OEt (1a), p-tolyl (1b)] were isolated from reactions of (IPr)Au(OTf) with the corresponding α-diazo carbonyl compounds...
Publikováno v:
Israel Journal of Chemistry. 60:437-445
Autor:
Ross A. Widenhoefer, Robert G. Carden
Publikováno v:
Chemistry – A European Journal. 25:11026-11030
The gold sulfonium benzylide complexes [(P1)AuCHPh(SR1 R2 )]+ {B[3,5-CF3 C6 H3 ]4 }- [P1=P(tBu)2 o-biphenyl; R1 , R2 =-(CH2 )4 - (1 a); R1 =Et, R2 =Ph (1 b); R1 =R2 =Ph (1 c)] were synthesized by reaction of the gold α-chloro benzyl complex (P1)AuCH