Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Ross A. Arthurs"'
Publikováno v:
European Journal of Organic Chemistry. 2021:2719-2725
Starting from (R)-Ugi's amine, diastereoselective lithiation followed by Ar'PCl 2 and then Ar’’MgBr led to the generation, as single diastereoisomers, of (R,S p,S phos) [Ar’=Ph, Ar’’=o-Tol] and (R,S p,R phos) [Ar’=o-Tol, Ar’’=Ph] PPFA
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d05edad6932d3bec0202dcdf60890137
https://doi.org/10.1002/ejoc.202100146
https://doi.org/10.1002/ejoc.202100146
Publikováno v:
The Journal of Organic Chemistry. 85:4838-4847
All four possible diastereoisomers of phosphinofer- rocenyloxazoline (Phosferrox type) ligands containing three elements of chirality were synthesized as single enantiomers. The S-c configured oxazoline moiety (R = Me, i-Pr) was used to control the g
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7558793dcb9957d9ecc291ca3e4be3b3
https://doi.org/10.1021/acs.joc.9b03342
https://doi.org/10.1021/acs.joc.9b03342
Publikováno v:
European Journal of Inorganic Chemistry. 2022
The palladium catalysed reaction of 1-iodo-2-methylnaphthalene and 2-methyl-1-naphthylmagnesium bromide gave quantitatively an ( S a )-configured cross-coupled product in 80% e.e. using ( R , S p )-PPFA as a ligand. N , N -Dimethylaminomethylferrocen
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5c9097f96a206133ec42c03349f74bd5
https://doi.org/10.1002/ejic.202101077
https://doi.org/10.1002/ejic.202101077
Publikováno v:
Organicbiomolecular chemistry. 18(28)
Chiral non-racemic palladacycles were employed as precatalysts for Pd(0) mediated asymmetric synthesis. Addition of HPAr2/base to a ferrocenyloxazoline planar chiral palladacycle resulted in ligand synthesis and palladium capture to give a bidentate
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2ae6e60a7af0e4a12b5bdd836ec593f8
https://pubmed.ncbi.nlm.nih.gov/32643748
https://pubmed.ncbi.nlm.nih.gov/32643748
Publikováno v:
European Journal of Inorganic Chemistry. 2018:1655-1659
The Friedel–Crafts acetylation of pentaphenylferrocene has been revisited using 1.1 equivalents of AcCl/AlCl3 in CH2Cl2 at room temperature leading to the synthesis of 1‐acetyl‐1′,2′,3′,4′,5′‐pentaphenylferrocene (78 % yield). Incre
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d568dfd1e22d863e5129dfe00b263993
https://doi.org/10.1002/ejic.201800129
https://doi.org/10.1002/ejic.201800129
Publikováno v:
Synlett. 29:585-588
Starting from (S,S)-1,1′-bis(4-isopropyloxazolin-2-yl)ferrocene, all possible 2-trimethylsilyl- and 2,2′-di(trimethylsilyl)-substituted diastereoisomers, potential bisoxazoline ligands for use in asymmetric catalysis, were synthesised by selectiv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fa653dc490c02ddb2cb78e5524f2679f
https://doi.org/10.1055/s-0036-1589163
https://doi.org/10.1055/s-0036-1589163
Reinvestigation of the palladation of (S)-2-ferrocenyl-4-(methylethyl)oxazoline with Pd(OAc)2 in CH2Cl2 was found to proceed with a dr of 3.6:1 in favor of the resulting S,Sp palladacycle. A similar 4:1 dr was obtained using Na2PdCl4 in MeOH. As an a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4cbb13de5ad866cc3b9c440b7633ddf5
https://ueaeprints.uea.ac.uk/id/eprint/73120/
https://ueaeprints.uea.ac.uk/id/eprint/73120/
Diastereoselective lithiation of (S)-2-ferrocenyl-4-(1-methylethyl)oxazoline, followed by addition of HgCl2, resulted in the formation by transmetalation of an (S,Sp)-configured mercury substituted complex. Addition to this of [Cp*IrCl2]2 and tetrabu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::008930bb4714753005db0290673b6870
https://eprints.soton.ac.uk/428805/
https://eprints.soton.ac.uk/428805/
Publikováno v:
European Journal of Inorganic Chemistry. 2017:229-232
Ferrocenyl (Fc) and phenyl (Ph) containing imines FcCH=NCH(R)Ph and FcCH(R)N=CHPh (R = H and Me) were cycloiridated using [Cp*IrCl2]2 with NaOAc in CH2Cl2. All resulted in the formation of neutral chloride ligated half-sandwich iridacycles as a resul
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::77e2fce36b5d9fea40beabe8caadb6c7
https://doi.org/10.1002/ejic.201600904
https://doi.org/10.1002/ejic.201600904
Autor:
Ross A. Arthurs, David L. Hughes, Vasily S. Oganesyan, Christopher Prior, Christopher J. Richards
Reaction of (η5-(S)-2-(4-methylethyl)oxazolinylcyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt with [IrCp*Cl2]2 in acetonitrile with KPF6 and KOt-Bu resulted in S,Sp,SIr and S,Rp,RIr configured acetonitrile and Cp* coordinated cationic iridac
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19650c37daeba8d9184a778083b8ef59
https://ueaeprints.uea.ac.uk/id/eprint/69836/
https://ueaeprints.uea.ac.uk/id/eprint/69836/