Zobrazeno 1 - 10
of 65
pro vyhledávání: '"Rory A. More O'Ferrall"'
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 6, Iss 1, Pp 1035-1042 (2010)
Solvolysis of trichloroacetate esters of 2-methoxy-1,2-dihydro-1-naphthols shows a remarkably large difference in rates between the cis and trans isomers, kcis/ktrans = 1800 in aqueous acetonitrile. This mirrors the behaviour of the acid-catalysed de
Externí odkaz:
https://doaj.org/article/2d6fd084071e4a3dba4586e2a1b71b9b
Autor:
Rory A. More O'Ferrall, Derek R. Boyd, Casey M. Lam, AnnMarie C. O'Donoghue, Michelle J. O'Mahony
Publikováno v:
Journal of Physical Organic Chemistry. 26:989-996
Rate constants have been determined by UV spectrophotometry at 25 °C for the acid-catalyzed dehydration of different types of monocyclic arene hydrates including those substituted at the 1-, 2- or 3-positions. General acid catalysis was not observed
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::802ae97395ca88b576b1f4d26814cf49
https://doi.org/10.1002/poc.3174
https://doi.org/10.1002/poc.3174
Publikováno v:
Journal of Physical Organic Chemistry. 26:1009-1015
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0cfcf5d6a0b9cd986278509910f5ca77
https://doi.org/10.1002/poc.3171
https://doi.org/10.1002/poc.3171
Autor:
Dara Coyne, Rory A. More O'Ferrall, David A. Lawlor, Aoife C. MacCormac, Derek R. Boyd, Jaya Satyanarayana Kudavalli
Publikováno v:
Journal of the American Chemical Society. 133:19718-19728
Cis- and trans-1,2-dihydrodiol isomers of benzene undergo acid-catalyzed dehydration to form phenol. In principle the isomeric substrates react through a common β-hydroxybenzenium (cyclohexadienyl) carbocation. Notwithstanding, the isomers show a la
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::abd585238f59737d98fb44ad38c6e69a
https://doi.org/10.1021/ja207160z
https://doi.org/10.1021/ja207160z
Publikováno v:
The Journal of Organic Chemistry. 76:9338-9343
Acid-catalyzed dehydrations of substituted naphthalene-cis-1,2-dihydrodiols occur with loss of the 1- or 2-OH group to form 2- and 1-naphthols, respectively. Effects of substituents MeO, Me, H, F, Br, I, and CN at 3-, 6-, and 7-positions of the napht
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0de9fa2741d356406b0d9410a155717
https://doi.org/10.1021/jo201591r
https://doi.org/10.1021/jo201591r
Publikováno v:
Journal of the American Chemical Society. 133:3381-3389
Thermodynamic stabilities of 92 carbenes, singlets and triplets, have been evaluated on the basis of hydrogenation enthalpies calculated at the G3MP2 level. The carbenes include alkyl-, aryl-, and heteroatom-substituted structures as well as cyclic 1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c0faf22cd5558ffb34e2032c53d3c3e4
https://doi.org/10.1021/ja1071493
https://doi.org/10.1021/ja1071493
Publikováno v:
ChemInform. 46
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b89ff2ca17239b600f3ea6900bdd622a
https://doi.org/10.1002/chin.201506292
https://doi.org/10.1002/chin.201506292
Publikováno v:
Journal of Physical Organic Chemistry. 17:631-640
The interconversion and hydrolysis of (E)- and (Z)-oximes of p-methoxybenzaldehyde in aqueous solutions of perchloric acid have been studied in the acid concentration range from pH 3 to 11M. Kinetic measurements confirm that isomerization and hydroly
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::627ff0d5c64357b9f746f3e3cfd9ab72
https://doi.org/10.1002/poc.780
https://doi.org/10.1002/poc.780
Autor:
Rory A. More O'Ferrall, and AnnMarie C. O'Donoghue, Aoife C. McCormack, S. Nagaraja Rao, Claire M McDonnell
Publikováno v:
Journal of the American Chemical Society. 124:8575-8583
Aqueous solvolyses of acyl derivatives of hydrates (water adducts) of anthracene and benzofuran yield carbocations which undergo competitive deprotonation to form the aromatic molecules and nucleophilic reaction with water to give the aromatic hydrat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f1487503f9d61e2c474d0fac48a28b2c
https://doi.org/10.1021/ja012613x
https://doi.org/10.1021/ja012613x
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :784-795
The equilibrium constant for keto–phenol tautomerisation of anthrone to 9-anthrol (KE = [phenol]/[ketone]) has been determined as pKE (−log KE) = 2.10 from ratios of rate constants for ketonisation of anthrol and phenolisation of anthrone in aque
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::82cb5a7fae303b80462acc4e57cb1ab2
https://doi.org/10.1039/b109242c
https://doi.org/10.1039/b109242c